P27127

Phenylquecksilberacetat

97%

• Synonym(e): Phenylmercurylacetat, Acetoxy-phenylquecksilber
• Lineare Formel: C₆H₅HgOCOCH₃
• CAS-Nummer: 62-38-4
• Molekulargewicht: 336.74
• Beilstein: 3662930
• EG-Nummer: 200-532-5
• MDL-Nummer: MFCD00008691
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24898353
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 97%
• Form: powder
• mp (Schmelzpunkt): 148-151 °C (lit.)
• SMILES String: CC(=O)O[Hg]c1ccccc1
• InChI: 1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1
• InChIKey: XEBWQGVWTUSTLN-UHFFFAOYSA-M

Beschreibung

Anwendung

Phenylmercuric acetate (PMA) can react with a palladium salt such as palladium acetate to form an arylpalladium salt in situ, which then reacts with primary or secondary allylic alcohols to produce 3-aryl aldehydes.[1] It can also be used in the multi-step synthesis of 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl thiol via Floyd′s pathway.[2]

Haftungsausschluss

For U.S. Customers: Contains mercury; Do not place in trash - dispose according to local, state, or federal laws.

Sicherheitshinweise

• Piktogramme: GHS06,GHS08,GHS05,GHS09
• Signalwort: Danger
• H-Sätze: H300,H314,H372,H410
• P-Sätze: P260 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 1
• Zielorgane: Kidney,Central nervous system
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges