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Merck

746762

Sigma-Aldrich

Lithiumhexafluorophosphat -Lösung

greener alternative

in ethyl methyl carbonate, 1.0 M LiPF6 in EMC, battery grade

Synonym(e):

1.0 M LiPF6 EMC, 1.0 M LiPF6 MEC

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About This Item

Lineare Formel:
LiPF6
MDL-Nummer:
UNSPSC-Code:
26111700
PubChem Substanz-ID:
NACRES:
NA.23

Qualität

battery grade

Qualitätsniveau

Form

solution

Grünere Alternativprodukt-Eigenschaften

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Konzentration

(1.0 M LiPF6 in EMC)

Verunreinigungen

<15 ppm H2O
<50 ppm HF

Farbe

APHA: <50

bp

100 °C

Dichte

1.12 g/mL at 25 °C (lit.)

Anionenspuren

chloride (Cl-): ≤1 ppm
sulfate (SO42-): ≤2 ppm

Kationenspuren

Ca: ≤1 ppm
Fe: ≤1 ppm
K: ≤1 ppm
Na: ≤1 ppm
Pb: ≤1 ppm

Anwendung(en)

battery manufacturing

Grünere Alternativprodukt-Kategorie

SMILES String

F[P-](F)(F)(F)(F)F.[Li+]

InChI

1S/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1

InChIKey

AXPLOJNSKRXQPA-UHFFFAOYSA-N

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Allgemeine Beschreibung

Lithium hexafluorophosphate solution in ethyl methyl carbonate is a class of electrolytic solution that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Anwendung

LiPF6 EMC is widely used as an electrolyte that is thermally stable in solvents. It can be mainly used in the fabrication of lithium-ion batteries.
Liquid electrolyte solutions play a key role in lithium ion batteries (LIB) acting as carrier of lithium ions between the cathode and anode. High purity and battery grade electrolyte solutions are thus crucial for lithium ion battery performance. The most common LIB electrolytes are derived from solutions of lithium salt, such as LiPF6 in non-aqueous solvents, example alkyl carbonates or solvent blend. The choice of the electrolyte solution is dependent on both the operating conditions like temperature and the nature of the electrode material in the LIB. The performance of the electrolyte solutions can be further modified with appropriate additives.

The ready-to-use electrolyte solutions are available in different solvent blends and can support a wide variety of lithium ion battery applications. These solutions are high purity and battery grade thus making them also suitable as standards in LIB research. Customized formulations can be made by inter-mixing the electrolyte solutions or by mixing appropriate of additives.

Sonstige Hinweise

Handling instructions:
  • Do not use with glass equipment
  • All work should be done very quickly under dry air to prevent electrolytes from water uptake and solvent vaporization.

Rechtliche Hinweise

Product of MU Ionic Solutions Corp

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT RE 1 Inhalation

Zielorgane

Bone,Teeth

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

77.0 °F

Flammpunkt (°C)

25 °C


Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Hexafluorophosphate intercalation into graphite electrode from ethylene carbonate/ethylmethyl carbonate
Fan H, et al.
Solid State Ionics, 304, 107-112 (2017)
Thermal stability of LiPF6 salt and Li-ion battery electrolytes containing LiPF6
Yang H, et al.
Journal of Power Sources, 161(1), 573-579 (2006)
Lucht, B. L.;
Energy Production and Storage, 333-333 (2010)
Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte
Liu J, et al.
Transactions of Nonferrous Metals Society of China, 20(2), 344-348 (2010)
Lex-Balducci, A.;
Lithium-Ion Batteries, 147-147 (2012)

Artikel

Solid-state Li batteries: Review of solid electrolytes, ion conduction, structures, and electrochemical processes.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

The critical technical challenges associated with the commercialization of electric vehicle batteries include cost, performance, abuse tolerance, and lifespan.

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