692220

(R)-Ru(OAc)₂(BINAP)

• Synonym(e): Diacetato-[(R)-(+)-2,2′-bis-(diphenylphosphino)-1,1′−binaphthyl]-ruthenium(II)
• Empirische Formel (Hill-System): C₄₈H₃₈O₄P₂Ru
• CAS-Nummer: 325146-81-4
• Molekulargewicht: 841.83
• MDL-Nummer: MFCD09753020
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 329761476
• NACRES: NA.22

Eigenschaften

• Form: powder
• Lagertemp.: 2-8°C
• SMILES String: CC(=O)O[Ru]OC(C)=O.c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
• InChI: 1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);/q;;;+2/p-2
• InChIKey: NMLZYEWNUCRSRJ-UHFFFAOYSA-L

Beschreibung

Anwendung

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-Ru(OAc)₂(BINAP) may be used as a catalyst for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins. It can also catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.

Catalyst for:

• Asymmetric hydrogenation reactions

Rechtliche Hinweise

Sold in collaboration with Takasago for research purposes only.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable