692255

RuCl₂[(R)−DM−BINAP][(R)−DAIPEN]

• Synonym(e): Dichlor-[(R)−2,2′−bis-[di-(3,5−xylyl)-phosphino]−1,1′−binaphthyl]-[(2R)−1,1−bis-(4−methoxyphenyl)−3−methyl−1,2−butandiamin]-ruthenium(II)
• Empirische Formel (Hill-System): C₇₁H₇₄Cl₂N₂O₂P₂Ru
• CAS-Nummer: 220114-32-9
• Molekulargewicht: 1221.28
• MDL number: MFCD09753026
• UNSPSC Code: 12352101
• PubChem Substance ID: 329761478
• NACRES: NA.22

Eigenschaften

• form: powder
• Quality Segment: 100
• reaction suitability: reagent type: catalyst; core: ruthenium; reaction type: Noyori Asymmetric Hydrogenation
• mp: 197-211 °C
• storage temp.: 2-8°C
• SMILES string: COc1ccc(cc1)C2([NH2][Ru]3(Cl)(Cl)([NH2][C@@H]2C(C)C)[PH](c4cc(C)cc(C)c4)(c5cc(C)cc(C)c5)c6ccc7ccccc7c6-c8c(ccc9ccccc89)[PH]3(c%10cc(C)cc(C)c%10)c%11cc(C)cc(C)c%11)c%12ccc(OC)cc%12
• InChI: 1S/C52H48P2.C19H26N2O2.2ClH.Ru/c1-33-21-34(2)26-43(25-33)53(44-27-35(3)22-36(4)28-44)49-19-17-41-13-9-11-15-47(41)51(49)52-48-16-12-10-14-42(48)18-20-50(52)54(45-29-37(5)23-38(6)30-45)46-31-39(7)24-40(8)32-46;1-13(2)18(20)19(21,14-5-9-16(22-3)10-6-14)15-7-11-17(23-4)12-8-15;;;/h9-32H,1-8H3;5-13,18H,20-21H2,1-4H3;2*1H;/t;18-;;;/m.1.../s1
• InChI key: VMSNEARTLSFOHB-OEGAAENXSA-N

Beschreibung

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Catalyst for:

• Noyori-type enantioselective ketone hydrogenation
• Enantioselective and asymmetric hydrogenation of ketones

Legal Information

Sold in collaboration with Takasago for research purposes only. JP Registration No. 2041996, 2731377, 2935453 JP Application No. 19970359654

Sicherheitshinweise

• Lagerklasse: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable