If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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693065
(R)-BINAP
Synonym(e):
(R)-(+)-2,2′-Bis(diphenylphosphin)-1,1′-binaphthalin, (R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl, (R)-(+)-1,1′-Binaphthalin-2,2′-diyl-bis-(diphenylphosphin), (R)-(+)-BINAP
Größe auswählen
| Größe/SKU | Verfügbarkeit | Preis |
|---|---|---|
100 mg | Warenkorb auf Verfügbarkeit prüfen | € 30,10 |
500 mg | Warenkorb auf Verfügbarkeit prüfen | € 82,20 |
Über diesen Artikel
form
crystals
Quality Segment
optical activity
[α]20/D +222°, c = 0.5% in benzene
reaction suitability
reaction type: Asymmetric synthesis, reagent type: ligand
reaction type: Noyori Asymmetric Hydrogenation
mp
239-241 °C (lit.)
functional group
phosphine
SMILES string
c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8
InChI
1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
InChI key
MUALRAIOVNYAIW-UHFFFAOYSA-N
Application
Legal Information
1 of 1
Dieser Artikel | |||
|---|---|---|---|
| description - | description 97% | description - | description technical grade |
| reaction suitability reagent type: ligand | reaction suitability - | reaction suitability reaction type: Asymmetric synthesis, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reagent type: ligand | reaction suitability reaction type: Asymmetric synthesis, reagent type: ligand |
| form crystals | form solid | form solid | form powder |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| optical activity [α]20/D +222°, c = 0.5% in benzene | optical activity [α]19/D +233°, c = 0.3 in toluene | optical activity [α]20/D +162°, c = 0.5 in benzene | optical activity - |
| mp 239-241 °C (lit.) | mp 239-241 °C (lit.) | mp 254-258 °C | mp - |
Lagerklasse
11 - Combustible Solids
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
PSA (Persönliche Schutzausrüstung)
Eyeshields, Gloves, type N95 (US)
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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