665479

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)piperidin

97%

• Synonym(e): (S)-(+)-4-Dinaphtho[2,1-d:1′,2′-f][1,3,2]-dioxaphosphepin-4-yl-piperidin, (S)-PipPhos
• Empirische Formel (Hill-System): C₂₅H₂₂NO₂P
• Molekulargewicht: 399.42
• MDL-Nummer: MFCD08276865
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24884739

Eigenschaften

• Assay: 97%
• Form: solid
• mp (Schmelzpunkt): 206-213 °C
• SMILES String: C1CCN(CC1)P2Oc3ccc4ccccc4c3-c5c(O2)ccc6ccccc56
• InChI: 1S/C25H22NO2P/c1-6-16-26(17-7-1)29-27-22-14-12-18-8-2-4-10-20(18)24(22)25-21-11-5-3-9-19(21)13-15-23(25)28-29/h2-5,8-15H,1,6-7,16-17H2
• InChIKey: ZYDGLCZCEANEHK-UHFFFAOYSA-N

Beschreibung

Anwendung

DSM MonoPhos Family of Highly Efficient Privileged Ligands

Asymmetric hydrogenation of N-aryl imines[1]

Phosphoramidite ligand used in a rhodium-catalyzed enantioselective 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.[2]

Rechtliche Hinweise

Sold under license from DSM for research purposes only.

Sicherheitshinweise

• Lagerklassenschlüssel: 13 - Non Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)