526134

tert-Butyldimethylsilylglycidylether

98%

• Empirische Formel (Hill-System): C₉H₂₀O₂Si
• CAS-Nummer: 78906-15-7
• Molekulargewicht: 188.34
• MDL-Nummer: MFCD02683555
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24874536
• NACRES: NA.22

Eigenschaften

• Assay: 98%
• Brechungsindex: n20/D 1.531 (lit.)
• bp: 195-197 °C (lit.)
• Dichte: 0.901 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: ether
• SMILES String: CC(C)(C)[Si](C)(C)OCC1CO1
• InChI: 1S/C9H20O2Si/c1-9(2,3)12(4,5)11-7-8-6-10-8/h8H,6-7H2,1-5H3
• InChIKey: YANSSVVGZPNSKD-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

tert-Butyldimethylsilyl glycidyl ether [tert-butyl-dimethyl-(oxiran-2-ylmethoxy)silane] can be synthesized from glycidol, via hydrolytic kinetic resolution (HKR) in the presence of R-(salen)Co complex and water.[1]

Anwendung

tert-Butyldimethylsilyl glycidyl ether may be used to synthesize (R/S)-1-benzylamino-3-(tert-butyldimethylsilyloxy)propan-2-ol and (2R/2S)-1-(tert-butyldimethylsilyloxy)-3-{[(4S)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl]amino}propan-2-ol.[2]

Sicherheitshinweise

• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 158.0 °F - closed cup
• Flammpunkt (°C): 70 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)