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Merck

481130

Sigma-Aldrich

Gold(I)-chlorid

99.9% trace metals basis

Synonym(e):

Aurous chloride, Gold monochloride

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€ 284,00
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€ 1.120,00

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1 G
€ 284,00
5 G
€ 1.120,00

About This Item

Lineare Formel:
AuCl
CAS-Nummer:
Molekulargewicht:
232.42
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.23

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Qualität

for analytical purposes

Qualitätsniveau

Assay

99.9% trace metals basis

Form

powder

Eignung der Reaktion

reagent type: catalyst
core: gold

Verunreinigungen

≤1500 ppm Trace Metal Analysis

mp (Schmelzpunkt)

289 °C (dec.) (lit.)

Dichte

7.57 g/mL at 25 °C (lit.)

SMILES String

[Cl-].[Au+]

InChI

1S/Au.ClH/h;1H/q+1;/p-1

InChIKey

FDWREHZXQUYJFJ-UHFFFAOYSA-M

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Allgemeine Beschreibung

Gold(I) chloride is a yellow crystalline solid with a monoclinic structure. It sublimes at elevated temperatures. Gold(III)chloride is thermally decomposed to produce gold(I) chloride. It is widely used as a precursor to prepare gold nanoparticles and catalyst systems.

Anwendung

Gold(I) chloride can be used:
  • As a precursor to prepare magnetic nanocatalyst systems for various organic transformations. For example, Fe3O4@SiO2-P–AuCl can be used as a catalyst for one-pot reductive amination of aldehydes and ketones with various aromatic amines.[1]
  • As a starting material to synthesize Au-containing complexes for application in the field of drug delivery, solar cells, sensors, and organic synthesis.[2]
  • As a precatalyst for stereoselective cycloisomerization of α-thioallenes to 2,5-dihydrothiophenes via C-S bond formation.[3]
  • As a catalyst for the conversion of siloxy cyclohexadienes, to the corresponding1,2- and 1,3-cyclohexenones via Gold-Catalyzed Cycloisomerization.[4]

Piktogramme

CorrosionExclamation mark

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Skin Corr. 1B - Skin Sens. 1

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Analysenzertifikate (COA)

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In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Gold-Catalyzed Cycloisomerization of Siloxy Enynes to Cyclohexadienes
Liming Zhang and Sergey A. Kozmin
Journal of the American Chemical Society, 126, 11806-11807 (2004)
Based on magnetic nanoparticles: Gold reusable nanomagnetic catalysts in organic synthesis
Mosstafa Kazemi
Synthetic Communications, 50, 2079-2094 (2020)
Au-containing coordination polymers based on polyphosphorus ligand complexes
Helena Brake, et al.
Inorganic Chemistry, 60, 6027-6039 (2021)
The First Gold-Catalyzed C?S Bond Formation: Cycloisomerization of ?-Thioallenes to 2,5-Dihydrothiophenes
Nobuyoshi Morita
Angewandte Chemie (International Edition in English) (2006)
A comparative study of galvanic replacement reactions involving Ag nanocubes and AuCl2? or AuCl4?
Au L, et al.
Advanced Materials, 20(13), 2517-2517 (2008)

Artikel

Access gold precatalysts, silver salts, and unsaturated building blocks to accelerate research success in catalysis applications.

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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