405418

2,6-Bis(chlormethyl)pyridin

99%

• Synonym(e): α,α′-Dichlor-2,6-lutidin
• Empirische Formel (Hill-System): C₇H₇Cl₂N
• CAS-Nummer: 3099-28-3
• Molekulargewicht: 176.04
• Beilstein: 116355
• MDL-Nummer: MFCD00142844
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24865315
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 99%
• Form: solid
• mp (Schmelzpunkt): 73-78 °C (lit.)
• Funktionelle Gruppe: chloro
• SMILES String: ClCc1cccc(CCl)n1
• InChI: 1S/C7H7Cl2N/c8-4-6-2-1-3-7(5-9)10-6/h1-3H,4-5H2
• InChIKey: IWQNFYRJSVJWQA-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

2,6-Bis(chloromethyl)pyridine is a heterocyclic building block for the synthesis of a variety of pyridine derivatives. It coordinates with metal ions through N-atom to form complexes. The conformational flexibility of the bromomethyl arms makes it an ideal choice for the generation of macrocycles. 2,6-bis(chloromethyl)pyridine crystals are monoclinic with space group P2₁/c. Its synthesis has been reported. The FT-IR and FT-Raman spectra of 2,6-bis(chloromethyl)pyridine (BCMP) have been recorded in the regions 4000-400cm^-1 and 3500-100cm^-1, respectively.

Anwendung

2,6-Bis(chloromethyl)pyridine may be used in the following studies:

• Synthesis of a sensitive fluorescent chemosensor for Hg²⁺, composed of two aminonaphthalimide fluorophores and a receptor of 2,6-bis(aminomethyl)pyridine.
• Preparation of carbene pincer ligands, required for the preparation of palladium pincer carbene complex.
• Synthesis of 2-(di-tert-butylphosphinomethyl)-6-diethylaminomethyl)pyridine, PNN ligand.

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H302,H315,H318,H335
• P-Sätze: P261 - P280 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves