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147532

Sigma-Aldrich

1,3,5-Benzoltricarbonyltrichlorid

98%

Synonym(e):

Benzol-1,3,5-tricarbonyl-chlorid, Trimesinsäuretrichlorid, Trimesoyl-chlorid

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About This Item

Lineare Formel:
C6H3(COCl)3
CAS-Nummer:
4422-95-1
Molekulargewicht:
265.48
Beilstein:
2940936
EG-Nummer:
224-594-8
MDL-Nummer:
MFCD00000679
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24848560
NACRES:
NA.23
Preise und Verfügbarkeit sind derzeit nicht verfügbar.

Qualitätsniveau

200

Assay

98%

Form

solid

bp

180 °C/16 mmHg (lit.)

mp (Schmelzpunkt)

32-38 °C (lit.)

Löslichkeit

chloroform: soluble 10%, clear to very slightly hazy, colorless to faintly yellow

Dichte

1.487 g/mL at 25 °C (lit.)

SMILES String

ClC(=O)c1cc(cc(c1)C(Cl)=O)C(Cl)=O

InChI

1S/C9H3Cl3O3/c10-7(13)4-1-5(8(11)14)3-6(2-4)9(12)15/h1-3H

InChIKey

UWCPYKQBIPYOLX-UHFFFAOYSA-N

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Verwandte Kategorien

Allgemeine Beschreibung

1,3,5-Benzoltricarbonyltrichlorid reagiert mit Propargylalkohol, um Triprop-2-inylbenzol-1,3,5-tricarboxylat zu erzeugen[1].

Anwendung

1,3,5-Benzoltricarbonyltrichlorid wird für die Synthese von chiralen, azoaromatischen, dendrimeren Systemen eingesetzt[2]. Es wurde zur Untersuchung der Struktur von aktivierten Verbundmembranen eingesetzt, die phosphororganische Extrakte als Träger enthalten.[3]. Es war das Ausgangsmaterial für zwei tritope Amide, die von 3- und 4-Methylaminopyridin abgeleitet wurden, das sich bei der Behandlung mit Palladium(II)-Nitrat in DMSO selbst zu Nanobällen organisierte.[4]

Piktogramme

CorrosionExclamation mark
GHS05,GHS07

Signalwort

Danger

H-Sätze

H314,H317

Gefahreneinstufungen

Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Lagerklassenschlüssel

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flammpunkt (°F)

230.0 °F - closed cup

Flammpunkt (°C)

110 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number
SHBR5629
SHBR5563
SHBR6448
SHBS2756
SHBR1712

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3,4'-DIAMINOBIPHENYL AldrichCPR

S933341

3,4'-DIAMINOBIPHENYL

Sushobhan Ghosh et al.
The Journal of organic chemistry, 71(22), 8412-8416 (2006-10-27)
The design and self-assembly of two new flexible supramolecular nanoballs are described. These assemblies incorporate two flexible tritopic amide and ester building blocks and were prepared in excellent yields (96-97%) via coordination driven self-assembly. The first resulted from the reaction
Luigi Angiolini et al.
Chirality, 22(1), 99-109 (2009-04-24)
New chiral azoaromatic dendrimeric systems have been synthesized starting from 1,3,5-benzenetricarbonyl trichloride as the core molecule. The simultaneous presence of the (S)-3-hydroxy pyrrolidinyl ring as the optically active moiety and the azobenzene donor-acceptor conjugated system as the photochromic group with
Behnam Khorshidi et al.
Scientific reports, 8(1), 784-784 (2018-01-18)
The development of nano-enabled composite materials has led to a paradigm shift in the manufacture of high-performance nanocomposite membranes with enhanced permeation, thermo-mechanical, and antibacterial properties. The major challenges to the successful incorporation of nanoparticles (NPs) to polymer films are
Zhe Yang et al.
Environmental science & technology, 52(16), 9341-9349 (2018-07-26)
Conventional thin-film composite (TFC) membranes suffer from the trade-off relationship between permeability and selectivity, known as the "upper bound". In this work, we report a high performance thin-film composite membrane prepared on a tannic acid (TA)-Fe nanoscaffold (TFCn) to overcome
Hyeon-Gyu Choi et al.
Chemosphere, 185, 1181-1188 (2017-08-05)
Thin-film composite mixed matrix membrane (TFC MMM) with functionalized carbon nanotube (fCNT) blended in polyethersulfone (PES) support layer was synthesized via interfacial polymerization and phase inversion. This membrane was firstly tested in lab-scale integrating seawater desalination and wastewater reclamation forward
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Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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