299685

Palladium(II)-trifluoracetat

97%, solid

• Synonym(e): Trifluoressigsäure Palladium(II)-salz
• Lineare Formel: (CF₃COO)₂Pd
• CAS-Nummer: 42196-31-6
• Molekulargewicht: 332.45
• UNSPSC Code: 12161600
• PubChem Substance ID: 24858054
• NACRES: NA.22
• MDL number: MFCD00013204

Eigenschaften

• Produktname: Palladium(II)-trifluoracetat, 97%
• Quality Segment: 200
• assay: 97%
• form: solid
• reaction suitability: core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst; reaction type: C-H Activation
• mp: ~220 °C
• SMILES string: FC(F)(F)C(=O)O[Pd]OC(=O)C(F)(F)F
• InChI: 1S/2C2HF3O2.Pd/c2*3-2(4,5)1(6)7;/h2*(H,6,7);/q;;+2/p-2
• InChI key: PBDBXAQKXCXZCJ-UHFFFAOYSA-L

Beschreibung

General description

Palladium(II) trifluoroacetate is a catalyst used in Suzuki-Miyaura, Heck, and Stille cross-coupling reactions.

Application

Catalyst used for the mild decarboxylation of electron-rich aromatic acids and the direct cross-coupling of unactivated arenes.

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Catalyzes the selective allylic oxidation of geranylacetone and other olefins to their allyl acetates, which can then be converted to keto alcohols.

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• Gefahrencodes: H315,H319,H335
• Sicherheitshinweise: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklasse: 11 - Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• PSA (Persönliche Schutzausrüstung): dust mask type N95 (US), Eyeshields, Gloves