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Sigma-Aldrich

Cyclopentadienylmangan(I)-tricarbonyl

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About This Item

Lineare Formel:
C5H5Mn(CO)3
CAS-Nummer:
12079-65-1
Molekulargewicht:
204.06
EG-Nummer:
235-142-4
MDL-Nummer:
MFCD00001440
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24857312
NACRES:
NA.23

Form

powder or crystals

Zusammensetzung

Mn, 26.0-27.9% EDTA titration

Eignung der Reaktion

core: manganese
reagent type: catalyst

mp (Schmelzpunkt)

72-76 °C (lit.)

SMILES String

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;

InChIKey

CZPHEHHRMHXAIK-UHFFFAOYSA-N

Verwandte Kategorien

Piktogramme

Skull and crossbones
GHS06

Signalwort

Danger

H-Sätze

H300

Gefahreneinstufungen

Acute Tox. 2 Oral

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Analysenzertifikate (COA)

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Benzolchrom(0)-tricarbonyl 98%

Sigma-Aldrich

119318

Benzolchrom(0)-tricarbonyl

Katrin Splith et al.
Dalton transactions (Cambridge, England : 2003), 39(10), 2536-2545 (2010-02-25)
By combining organometallic groups and peptides, a large number of conjugates with interesting new biological properties can be prepared. Especially, attachment to cell-penetrating peptides (CPP) that act as efficient cell delivery vehicles has come to the fore. However, the presence
K T Blanchard et al.
Toxicology and applied pharmacology, 136(2), 280-288 (1996-02-01)
Cyclopentadienyl manganese tricarbonyl (CMT) produces acute pulmonary injury following cytochrome P450 mixed-function oxidase (CYP450) activation. The current studies were designed to characterize the role of hepatic and/or pulmonary CMT activation and the subsequent pneumotoxicity of this compound following subcutaneous injection
M Salmain et al.
Journal of immunological methods, 148(1-2), 65-75 (1992-04-08)
A new non-radioisotopic immunoassay procedure, which we have termed carbonylmetalloimmunoassay (CMIA), is described. The tracers used in this approach are organometallic carbonyl complexes that can be detected at femtomole levels (300-700 fmol) by Fourier transform infrared (FT-IR) spectroscopy. The validity
Sohrab Kheradmandan et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 8(11), 2526-2533 (2002-08-16)
The syntheses and X-ray crystal structures of [([18]crown-6)2Cs](+)-[Cp3Mn]- (1), [([18]crown-6)2Cs](+)-[Cp'3Mn]- (2), [CsCp'] (3), [(CsCp')2-([18]crown-6)] (4), and Cs[MnCp3] (5), and the synthesis of Cs[MnCp'3] (6) are reported (Cp' = C5H4Me). The anions [Cp3Mn]- (1-) and [Cp'3Mn]- (2-) are characterized by eta
Ilona Kopf et al.
The Analyst, 137(21), 4995-5001 (2012-09-12)
In this paper we investigate metal-organic compounds as infrared (IR) active labels by scattering scanning near-field infrared microscopy (IR s-SNOM, often also abbreviated as s-SNIM) with a lateral resolution of 90 × 90 nm(2). Tailor-made IR spectroscopic probes based on
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