931217
CX93
Umicore, powder
Synonym(s):
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), Dichloro[1,1′-bis(diphenylphosphino)ferrocene]palladium(II), Pd(dppf)Cl2
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| Size/SKU | Availability | Price |
|---|---|---|
1 g | Please contact Customer Service for Availability | $135.00 |
5 g | Please contact Customer Service for Availability | $421.00 |
25 g | Please contact Customer Service for Availability | $1,570.00 |
About This Item
Linear Formula:
(C17H14P)2Fe · PdCl2
CAS Number:
Molecular Weight:
731.70
NACRES:
NA.21
UNSPSC Code:
12352103
MDL number:
Product Name
CX93, Umicore
Quality Segment
form
powder
mp
266-283 °C (lit.)
storage temp.
2-8°C
SMILES string
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
InChI key
JCWIWBWXCVGEAN-UHFFFAOYSA-L
Application
CX93 is a catalyst for C-C and C-N coupling reaction. Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:-
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
Preparation Note
Do not store above 25 °C (77 °F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
Legal Information
Product of Umicore
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
Additional information available at www.pmc.umicore.com
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
Additional information available at www.pmc.umicore.com
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This Item | |||
|---|---|---|---|
| form powder | form crystals | form crystals | form crystals |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. - | storage temp. - | storage temp. - |
| mp 266-283 °C (lit.) | mp - | mp - | mp 239-241 °C (lit.) |
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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