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763381
XPhos Pd G3
98%, solid, 1:1 MTBE adduct
Synonym(s):
(2-Dicyclohexylphosphino-2′,4′,6′-triisopropyl-1,1′-biphenyl)[2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, XPhos-G3-Palladacycle, XPhos-Pd-G3
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 mg | Available to ship TODAYfromMILWAUKEE | $72.50 | |
| 1 g | Estimated to ship onMay 15, 2026fromMILWAUKEE | $232.00 | |
| 5 g | Available to ship TODAYfromMILWAUKEE | $1,020.00 | |
| 25 g | Available to ship TODAYfromMILWAUKEE | $4,300.00 |
About This Item
$72.50
Available to ship TODAYDetails
Product Name
XPhos Pd G3, 98%, 1:1 MTBE adduct
Quality Level
product line
Buchwald precatalyst Generation 3
assay
98%
form
solid
feature
generation 3
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
146-151 °C (decomposition)
functional group
phosphine
SMILES string
CC(C1=CC(C(C)C)=C(C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4)C(C(C)C)=C1)C.NC5=C(C=CC=C5)C6=C(C=CC=C6)[Pd]OS(C)(=O)=O
1 of 1
This Item | |||
|---|---|---|---|
| reaction suitability core: palladium, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalyst | reaction suitability - | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability - |
| assay 98% | assay - | assay 95% | assay 98% |
| functional group phosphine | functional group - | functional group phosphine | functional group phosphine |
| form solid | form solid | form solid | form solid |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 146-151 °C (decomposition) | mp - | mp 164-167 °C (decomposition) | mp 130-140 °C |
General description
Application
- Cyanation reaction of heterocyclic halides.
- Coupling of heteroaryl chlorides with polyfluoroaryl zinc reagents.
- Coupling of 2,6-difluorophenylboronic acid with (hetero)aryl chlorides.
related product
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.
G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
Preformed catalysts in the kit are stable but become air-sensitive when activated; Schlenk technique aids scale-up.
Tools aid in kit setup for organic chemistry techniques, ensuring ease and success.
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Global Trade Item Number
| SKU | GTIN |
|---|---|
| 763381-250MG | 04061832922836 |
| 763381-1G | 04061832922829 |
| 763381-25G | 04065271045347 |
| 763381-5G | 04061832922843 |
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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