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761435
cataCXium® A Pd G3
95%, solid
Synonym(s):
Mesylate[(di(1-adamantyl)-n-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II), [(Di(1-adamantyl)-butylphosphine)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate, cataCXium-A-Pd-G3
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 mg | Please contact Customer Service for Availability | $218.00 | |
| 1 g | Please contact Customer Service for Availability | $596.00 | |
| 5 g | Please contact Customer Service for Availability | $2,420.00 | |
| 25 g | Please contact Customer Service for Availability | $10,200.00 |
About This Item
Product Name
cataCXium® A Pd G3, 95%
Quality Level
product line
Buchwald precatalyst Generation 3
assay
95%
form
solid
feature
generation 3
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
greener alternative product score
old score: 16
new score: 2
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greener alternative product characteristics
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sustainability
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impurities
≤3% acetone
mp
196-241 °C (decomposition)
functional group
phosphine
greener alternative category
SMILES string
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7
InChI
1S/C24H39P.C12H10N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;
InChI key
REYVZCOGMIXVNX-DVBMAMJVSA-M
General description
Application
- Direct ortho-arylation of pyridinecarboxylic acids.
- Catalyzing Suzuki–Miyaura cross-coupling in the synthesis of 1-heteroaryl-3-azabicyclo[3.1.0]hexanes.
- Palladium-catalyzed carbonylative carboperfluoroalkylation of alkynes.
- Suzuki–Miyaura coupling reaction of geminal bis(boryl)cyclopropanes in the synthesis of various gem-disubstituted cyclopropanes.
- Boroperfluoroalkylation of terminal alkynes.
- Copper-free Sonogashira coupling reaction of aromatic halides with alkynes to form C-C bond.
- Suzuki cross-coupling between organotrifluoroborate and aryl halides.
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| assay 95% | assay - | assay - | assay 97% |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reaction type: Negishi Coupling, reagent type: catalyst | reaction suitability - | reaction suitability reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability - |
| form solid | form solid | form solid | form solid |
| mp 196-241 °C (decomposition) | mp - | mp 220 °C (decomposition) | mp 192-201 °C (decomposition) |
| impurities ≤3% acetone | impurities - | impurities - | impurities - |
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Related Content
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 761435-25G | 04065271045330 |
| 761435-1G | 04061826251935 |
| 761435-250MG | 04061832970622 |
| 761435-5G | 04061832970639 |
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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