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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
697230
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
powder
Synonym(s):
Pd(dppf)Cl2
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 1 g | Check Cart for Availability | $133.00 | |
| 5 g | Check Cart for Availability | $477.00 | |
| 25 g | Please contact Customer Service for Availability | $1,490.00 | |
| 250 g | Please contact Customer Service for Availability | $12,110.00 |
About This Item
Product Name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II),
form
powder
Quality Level
reaction suitability
core: palladium, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
mp
266-283 °C (lit.)
SMILES string
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
InChI key
JCWIWBWXCVGEAN-UHFFFAOYSA-L
Application
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
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Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Tandem hydroboration Suzuki Coupling both intermolecular and intramolecular gave diverse alkyl substituted products dppf
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 697230-5G | 04061832786308 |
| 697230-1G | 04061832786131 |
| 697230-25G | 04065271068131 |
| 697230-250G | 04061833550946 |
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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