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328774
Tris(dibenzylideneacetone)dipalladium(0)
97%, powder
Synonym(s):
Pd2dba3, Pd2(dba)3
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 500 mg | Available to ship TODAYfromMILWAUKEE | $44.70 | |
| 1 g | Available to ship TODAYfromMILWAUKEE | $73.50 | |
| 5 g | Available to ship TODAYfromMILWAUKEE | $275.00 | |
| 25 g | Available to ship TODAYfromMILWAUKEE | $1,040.00 | |
| 50 g | Available to ship TODAYfromMILWAUKEE | $1,950.00 | |
| 100 g | Available to ship TODAYfromMILWAUKEE | $3,500.00 | |
| 500 g | Estimated to ship onApril 20, 2026fromMILWAUKEE | $15,710.00 |
About This Item
$44.70
Available to ship TODAYDetails
Product Name
Tris(dibenzylideneacetone)dipalladium(0), 97%
Quality Level
assay
97%
form
powder
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp
152-155 °C (lit.)
SMILES string
[Pd].[Pd].O=C(\C=C\c1ccccc1)/C=C/c2ccccc2.O=C(\C=C\c3ccccc3)/C=C/c4ccccc4.O=C(\C=C\c5ccccc5)/C=C/c6ccccc6
InChI
1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;
InChI key
CYPYTURSJDMMMP-WVCUSYJESA-N
1 of 1
This Item | |||
|---|---|---|---|
| reaction suitability core: palladium, reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reaction type: Negishi Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst | reaction suitability - | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst |
| form powder | form solid | form powder | form powder |
| assay 97% | assay - | assay - | assay - |
| Quality Level 200 | Quality Level 100 | Quality Level 200 | Quality Level 100 |
| mp 152-155 °C (lit.) | mp - | mp 152-155 °C (lit.) | mp - |
General description
For small scale and high throughput uses, product is also available as ChemBeads (919772)
Application
- Application Guide for Palladium Catalyzed Cross-Coupling Reactions
- Synthesis of azepanes[2]
- Synthesis of nanosized palladium phosphides upon interaction with white phosphorous
- Preparation of palladium triphenylphosphine carbonyl cluster complexes
- Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions
- Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes
Reactant involved in:
- Catalyst for:
- Suzuki cross-coupling reactions
- PCN- and PCS-pincer palladium complex catalyzed tandem allylation
- Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
- Catalyst for Heck coupling of aryl chlorides (eq. 2)
- Catalyst for arylation of ketones (eq. 3)
- Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
- Catalyst for fluorination of allylic chlorides[3] (eq. 5)
- Catalyst for β-arylation of carboxylic esters[4] (eq. 6)
- Catalyst for carbonylation of 1,1-dichloro-1-alkenes[5] (eq. 7)
- Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides[6] (eq. 8)
- Pd source for enantioselective Tsuji Allylations
signalword
Warning
hcodes
Hazard Classifications
Aquatic Chronic 2 - Skin Sens. 1
Storage Class
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Related Content
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 328774-500MG | 04061826717790 |
| 328774-1G | 04061826717776 |
| 328774-100G | 04061833546635 |
| 328774-50G | 04061826717806 |
| 328774-500G | 04061833498965 |
| 328774-25G | 04061826717783 |
| 328774-5G | 04061826717813 |
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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