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Merck
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文件

P3011

Sigma-Aldrich

硫氰酸钾

ReagentPlus®, ≥99.0%

同義詞:

硫氰化钾

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About This Item

線性公式:
KSCN
CAS號碼:
分子量::
97.18
Beilstein:
3594799
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.55

產品線

ReagentPlus®

化驗

≥99.0%

形狀

powder or crystals

pH值

5.3-8.7 (25 °C, 97.2 g/L)

mp

173 °C (lit.)

SMILES 字串

[K]SC#N

InChI

1S/CHNS.K/c2-1-3;/h3H;/q;+1/p-1

InChI 密鑰

ZNNZYHKDIALBAK-UHFFFAOYSA-M

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一般說明

Potassium thiocyanate (KSCN) is a potassium salt of thiocyanate anion. Its crystalline structure has been analyzed based on polarized infrared spectral data. The inhibition efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been evaluated. It facilitates the ring opening of aziridines with high regioselectivity.

應用

Potassium thiocyanate may be used in the synthesis of the following:
  • α-Amino nitriles from tertiary amines.
  • Polysubstituted 2-aminothiazoles from vinyl azides.
  • Benzisothiazol-3(2H)-one derivatives from o-bromobenzamides.
  • Diaryl thioethers from aryl halides.

法律資訊

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1

安全危害

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Regioselective ring-opening of aziridines with potassium thiocyanate in the presence of β-cyclodextrin in water.
Reddy MS, et al.
Tetrahedron Letters, 46(38), 6437-6439 (2005)
Synthesis of diaryl thioethers from aryl halides and potassium thiocyanate.
Hajipour AR, et al.
Applied Organometallic Chemistry, 28(12), 879-879 (2014)
Potassium Thiocyanate as Source of Cyanide for the Oxidative α-Cyanation of Tertiary Amines.
Wagner A and Ofial AR.
The Journal of Organic Chemistry, 80(5), 2848-2854 (2015)
Iron (II)-Promoted Synthesis of 2-Aminothiazoles via C=N Bond Formation from Vinyl Azides and Potassium Thiocyanate.
Zhang G, et al.
Advanced Synthesis & Catalysis, 357(5), 1065-1069 (2015)
Polarized infrared spectrum of potassium thiocyanate.
Jones LH.
J. Chem. Phys. , 28(6), 1234-1236 (1958)

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