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63095

Sigma-Aldrich

高氯酸镁

puriss. p.a., drying agent, ACS reagent, ≥98.0% (calc. based on dry substance, KT)

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About This Item

線性公式:
Mg(ClO4)2
CAS號碼:
分子量::
223.21
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NB.24

等級

ACS reagent
drying agent
puriss. p.a.

化驗

≥98.0% (calc. based on dry substance, KT)

形狀

powder or chunks

雜質

≤0.005 meq/g free acid (as HClO4)
≤0.025 meq/g free alkali (as MgO)
≤8% water

負離子痕跡

chloride (Cl-): ≤50 mg/kg
nitrate (NO3-): ≤100 mg/kg
sulfate (SO42-): ≤500 mg/kg

正離子痕跡

Ca: ≤500 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤500 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES 字串

[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2

InChI 密鑰

MPCRDALPQLDDFX-UHFFFAOYSA-L

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一般說明

Magnesium perchlorate (Mg(ClO4)2) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.

應用

Magnesium perchlorate (Mg(ClO4)2) may be employed as a catalyst in the following studies:
  • Preparation of α-aminophosphonates.
  • Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.
  • Preparation of imines and phenylhydrazones.
  • Protection of alcohols in the form of t-butyl ethers.

象形圖

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訊號詞

Danger

危險分類

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

5.1A - Strongly oxidizing hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


分析證明 (COA)

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Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones.
Chakraborti AK, et al.
Tetrahedron Letters, 45(41), 7641-7644 (2004)
Eagleson M.
Concise Encyclopedia Chemistry, 343-343 (1994)
F Javier Céspedes-Guirao et al.
The Journal of organic chemistry, 74(16), 5871-5880 (2009-07-29)
Zinc phthalocyanine-perylenebisimide pentameric arrays, ZnPc(PDI)(4) 1 and 2, have been synthesized. ZnPc(PDI)(4) 1 has no substituents in the PDI bay positions, while ZnPc(PDI)(4) 2 presents four phenoxy groups in the bay positions of each perylene. In both cases, the PDI
J D Anastassopoulou
Magnesium research, 3(1), 19-21 (1990-03-01)
The mechanism of the gamma-radiolysis of the nucleotide guanosine-5'-monophosphate (5'-GMP) in the presence of Mg++ ions and cis-platinum was investigated. From high performance liquid chromatography and spectroscopy studies it was found that the OH radicals, produced in irradiated aqueous solutions
Srikant Bhagat et al.
The Journal of organic chemistry, 72(4), 1263-1270 (2007-01-27)
Commercially available magnesium perchlorate is reported as an extremely efficient catalyst for the synthesis of alpha-aminophosphonates. A three-component reaction (3-CR) of an amine, an aldehyde or a ketone, and a di-/trialkyl phosphite (Kabachnik-Fields reaction) took place in one pot under

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