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重要文件

8.03235

Sigma-Aldrich

N,N-二甲基乙酰胺

for synthesis

同義詞:

N,N-二甲基乙酰胺

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About This Item

線性公式:
CH3CON(CH3)2
CAS號碼:
分子量::
87.12
MDL號碼:
分類程式碼代碼:
12352111
酶委員會索引編號:
204-826-4
NACRES:
NA.22
bp:
165-166 °C/1013 hPa
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等級

for synthesis
synthesis grade

品質等級

蒸汽壓力

1.76 hPa ( 20 °C)

化驗

≥99% (GC)

形狀

liquid

自燃溫度

400 °C

效力

5830 mg/kg LD50, oral (Rat)

expl. lim.

1.7-11.5 % (v/v)

dilution

(for synthesis)

pH值

4 (20 °C, 200 g/L in H2O)

bp

165-166 °C/1013 hPa

mp

-20 °C

轉變溫度

flash point 64 °C

溶解度

soluble >1000 g/L

密度

0.94 g/cm3 at 20 °C

儲存溫度

2-30°C

SMILES 字串

N(C)(C)C(=O)C

InChI

1S/C4H9NO/c1-4(6)5(2)3/h1-3H3

InChI 密鑰

FXHOOIRPVKKKFG-UHFFFAOYSA-N

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一般說明

N,N-二甲基乙酰胺(DMAc)是一种可与水混溶的有机溶剂,用于苯乙烯、乙烯树脂、线形聚酯、丙烯酸纤维、塑料、杀虫剂和合成革的合成。它参与过渡金属的脱氢、脱水、卤化、去质子化反应和还原羰基化反应。它也可作为催化剂、促进剂、卤素/烷氧基或羟基/卤素交换介导子、还原剂和碱源。[1][2]

應用

N,N-二甲基乙酰胺可用作以下反应的溶剂:
  • 合成聚(酰胺-酰肼–石墨烯复合材料。[3]
  • 在三乙胺催化剂存在的情况下合成 N,N′-1,2-乙烷二基双-(4-羟基-戊酰胺) 和4-羟基-N-(2- 羟乙基)-戊酰胺基聚氨酯。[4]

特點和優勢

N,N-二甲基乙酰胺: :
  • 对于多种底物有高溶解力。 
  • 对阴离子有高溶剂化力。[2]

分析報告

含量(GC,area%): ≥ 99.0 %(a/a)
密度(d 20 °C/20 °C):0.940 - 0.942
水(K. F.): ≤ 0.30 %
同一性(IR):通过测试

象形圖

Exclamation markHealth hazard

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Repr. 1B

儲存類別代碼

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 2

閃點(°F)

147.2 °F - closed cup

閃點(°C)

64 °C - closed cup


分析證明 (COA)

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Elsabee MZ, et al.
Polymer Composites, 38(7), 1311-1318 (2017)
Synthesis and characterization of novel polyurethanes based on N, N'-1, 2-ethanediylbis-(4-hydroxy-pentanamide) and 4-hydroxy-N-(2-hydroxyethyl)-pentanamide
Chalid M
Advanced Materials Research, 277, 112-119 (2011)
Toxic hepatitis in occupational exposure to solvents
Malaguarnera G.et al.
World Journal of Gastroenterology, 18(22), 2756-2756 (2012)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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