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重要文件

B90602

Sigma-Aldrich

叔丁基苯

99%

同義詞:

2-甲基-2-苯基丙烷

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About This Item

線性公式:
C6H5C(CH3)3
CAS號碼:
分子量::
134.22
Beilstein:
1421537
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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蒸汽密度

3.16 (169 °C, vs air)

品質等級

蒸汽壓力

4.79 mmHg ( 37.7 °C)

化驗

99%

形狀

liquid

自燃溫度

842 °F

折射率

n20/D 1.492 (lit.)

bp

169 °C (lit.)

mp

−58 °C (lit.)

密度

0.867 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)(C)c1ccccc1

InChI

1S/C10H14/c1-10(2,3)9-7-5-4-6-8-9/h4-8H,1-3H3

InChI 密鑰

YTZKOQUCBOVLHL-UHFFFAOYSA-N

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一般說明

叔丁基苯,又称2-甲基-2-苯丙,一种芳烃,常作为合成砌块合成各种叔丁基衍生物。由于非极性特性,它是工业生产中的有效溶剂,特别适于涂料和粘合剂。[1]

應用

  • 气体分离应用: 叔丁基苯可用于通过共价交联合成芳香族聚酰亚胺膜,改善了其在气体分离过程中的性能,这一点对工业应用和环境管理中很关键(Lozano et al., 2022)。
  • 增进拉曼散射:在纳米间隙增强拉曼散射研究中,该化合物可用作金属纳米颗粒的底物,这对分析化学很关键,为各种化合物提供了灵敏的检测方法 (Chen et al., 2021)。
  • 超极化(13)C探针:它对超极化(13)C探针的合理设计很关键,使磁共振成像(MRI)技术取得重大进步,提高了诊断成像能力(Sando et al., 2018)。

象形圖

FlameExclamation mark

訊號詞

Warning

危險聲明

危險分類

Flam. Liq. 3 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

116.6 °F - closed cup

閃點(°C)

47 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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存取文件庫

De-tert-butylation of substituted arenes
Saleh et al.
Tetrahedron, 54, 14157-14177 (1998)
Liquid density measurements of cumene, tert-butylbenzene, and hexadecane over wide ranges of temperature and pressure
Khasanshin et al.
Fluid Phase Equilibria, 463, 121-127 (2018)
The Orientation of Isopropyl and tert-Butyl Groups in Benzene Dialkylation
Hennion et al.
The Journal of Organic Chemistry, 17, 1102-1106 (1952)
Clément Bonnot et al.
Journal of the American Chemical Society, 126(37), 11412-11413 (2004-09-16)
Compound 1, a cryptand-derived macropentacycle, is a flexible molecule that encompasses many conformations (symmetrical, unsymmetrical, and chiral ones) depending on the observation temperature (VT 1H NMR). Selective monoprotonation of this molecule leads to a totally unsymmetrical, rigidly chiral species in
Salvatore Fanali et al.
Journal of separation science, 29(10), 1423-1431 (2006-08-10)
Several racemic acidic compounds of pharmaceutical and environmental interest have been separated into their enantiomers by nano-liquid chromatography (nano-LC) employing a tert-butylbenzoylated tartardiamide chiral stationary phase (CHI-TBB). CHI-TBB was packed into a fused silica capillary of 100 microm id and

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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