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A71301

Sigma-Aldrich

2-氨基苯酚

99%

同義詞:

(2-羟苯基)胺, 1-羟基-2-氨基苯, 2-氨基-1-羟基苯, 2-氨基苯基乙醇, 2-氨基苯酚, 2-羟基苯胺, 2-羟苯胺, o-氨基羟基苯, o-羟基苯胺, o-羟苯胺

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About This Item

線性公式:
H2NC6H4OH
CAS號碼:
95-55-6
分子量：:
109.13
Beilstein:
606075
EC號碼:
202-431-1
MDL號碼:
MFCD00007690
分類程式碼代碼:
12352100
PubChem物質ID:
24891176
NACRES:
NA.22
暫時無法取得訂價和供貨情況

化驗

99%

形狀

powder

mp

170-175 °C (lit.)

SMILES 字串

Nc1ccccc1O

InChI

1S/C6H7NO/c7-5-3-1-2-4-6(5)8/h1-4,8H,7H2

InChI 密鑰

CDAWCLOXVUBKRW-UHFFFAOYSA-N

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相關類別

應用

2-氨基苯酚可用于合成：
  • 与β氨基醇在Pd/C-I2催化下通过氧化环羰基化反应合成2-噁唑烷酮衍生物。[1]
  • 与亚水杨基-4-氨基安替比林合成席夫碱过渡金属(II)配合物。[2]
  • 在富氧气氛、活性碳催化下与醛合成2-芳基苯并噁唑。[3]

象形圖

Health hazardExclamation mark
GHS08,GHS07

訊號詞

Warning

危險聲明

H302 + H332,H341

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Muta. 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 2

閃點（°F）

334.4 °F - closed cup

閃點（°C）

168 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析證明 (COA)

Lot/Batch Number
STBL3085
STBK4803
STBK3153
STBJ2458
STBH1563

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Synthesis of 2-oxazolidinone catalyzed by palladium on charcoal: a novel and highly effective heterogeneous catalytic system for oxidative cyclocarbonylation of β -aminoalcohols and 2-aminophenol.
Li F and Xia C
J. Catal., 227(2), 542-546 (2004)
Synthesis, spectroscopic characterization, redox, and biological screening studies of some Schiff base transition metal (II) complexes derived from salicylidene-4-aminoantipyrine and 2-aminophenol/2-aminothiophenol.
Raman N, et al.
Synth. React. Inorg. Met.-Org. Chem. , 31(7), 1249-1270 (2001)
Michael M Bittner et al.
Journal of the American Chemical Society, 134(12), 5460-5463 (2012-03-16)
The oxidative ring cleavage of aromatic substrates by nonheme Fe dioxygenases is thought to involve formation of a ferrous-(substrate radical) intermediate. Here we describe the synthesis of the trigonal-bipyramdial complex Fe((Ph2)Tp)(ISQ(tBu)) (2), the first synthetic example of an iron(II) center
Yoshinori Endo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(43), 13609-13613 (2012-09-13)
Aerobic oxidation: in a biomimetic approach, a mixture of redox catalysts forms couples that effect the aerobic oxidation of a mixture of benzylamine and 2-aminophenol derivatives to give the corresponding benzoxazoles. This biomimetic oxidation proceeds smoothly under mild conditions and
Ericsson D Coy et al.
Organic letters, 12(9), 1976-1979 (2010-03-27)
An efficient and facile synthesis of trans-dihydrobenzofurans has been accomplished from o-aminophenols and phenylpropenes via a novel (one-pot) diastereoselective Pd-catalyzed oxyarylation reaction. The development and optimization of this method is described.
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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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