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922919

Sigma-Aldrich

Pd(IPr)(acac)Cl

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經驗公式(希爾表示法):
C32H43ClN2O2Pd
CAS號碼:
分子量::
629.57
MDL號碼:
分類程式碼代碼:
12352103
NACRES:
NA.22
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形狀

powder

品質等級

反應適用性

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

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描述
訂價

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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[Pd(NHC)(acac)Cl]: Well-Defined, Air-Stable, and Readily Available Precatalysts for Suzuki and Buchwald−Hartwig Cross-coupling (Transamidation) of Amides and Esters by N−C/O−C Activation.
Zhou T, et al.
Organic Letters, 21, 3304-3309 (2019)
Nicolas Marion et al.
The Journal of organic chemistry, 71(10), 3816-3821 (2006-05-06)
A very straightforward synthesis of (IPr)Pd(acac)Cl from two commercially available starting materials, Pd(acac)2 and IPr.HCl [acac = acetylacetonate; IPr = N,N'-bis(2,6-diisopropylphenyl)imidazol-2-ylidene], has been developed. The resulting complex, (IPr)Pd(acac)Cl (1), has proven to be a highly active PdII precatalyst in the

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