推薦產品
品質等級
化驗
≥95%
形狀
powder or crystals
反應適用性
reaction type: Photocatalysis
reagent type: catalyst
儲存溫度
−20°C
SMILES 字串
B(F)(F)F.[F-].FC(F)(F)c1ccc(cc1)[n+]2c3c(c(c5c2cc(cc5)C(C)(C)C)c4c(cccc4C)C)ccc(c3)C(C)(C)C
InChI
1S/C36H37F3N.BF3.FH/c1-22-10-9-11-23(2)32(22)33-28-18-14-25(34(3,4)5)20-30(28)40(27-16-12-24(13-17-27)36(37,38)39)31-21-26(35(6,7)8)15-19-29(31)33;2-1(3)4;/h9-21H,1-8H3;;1H/q+1;;/p-1
InChI 密鑰
XITZTMKZLKVHKJ-UHFFFAOYSA-M
應用
3,6-Di-tert-butyl-9-(2,6-dimethylphenyl)-10-(4-(trifluoromethyl)phenyl)acridin-10-ium tetrafluoroborate is a robust acridinium-based photocatalyst reported by Nicewicz and coworkers as an alternative to transition-metal-based photocatalysts with higher chemical stability and attenuated redox potential.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
相關產品
產品號碼
描述
訂價
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
Journal of the American Chemical Society, 142(40), 17187-17194 (2020-09-29)
Nucleophilic aromatic substitution (SNAr) is a classical reaction with well-known reactivity toward electron-poor fluoroarenes. However, electron-neutral and electron-rich fluoro(hetero)arenes are considerably underrepresented. Herein, we present a method for the nucleophilic defluorination of unactivated fluoroarenes enabled by cation radical-accelerated nucleophilic aromatic
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