804150

SnAP 2,3-Bicyclo-(3,4-Pyr)M试剂

• 同義詞: (3R,4R)-tert-butyl 3-amino-4-((tributylstannyl)methoxy) pyrrolidine-1-carboxylate
• 經驗公式（希爾表示法）: C₂₂H₄₆N₂O₃Sn
• 分子量：: 505.32
• MDL號碼: MFCD30491293
• 分類程式碼代碼: 12352103
• PubChem物質ID: 329768847
• NACRES: NA.22

屬性

• 形狀: liquid
• 品質等級: 100
• 密度: 1.180 at 25 °C
• 官能基: ether
• 儲存溫度: −20°C
• SMILES 字串: CCCC[Sn](CCCC)(CO[C@H]1CN(C(OC(C)(C)C)=O)C[C@@H]1N)CCCC
• InChI: 1S/C10H19N2O3.3C4H9.Sn/c1-10(2,3)15-9(13)12-5-7(11)8(6-12)14-4;3*1-3-4-2;/h7-8H,4-6,11H2,1-3H3;3*1,3-4H2,2H3;/t7-,8-;;;;/m0..../s1
• InChI 密鑰: URTKNAYUDTUPJM-CFACWHMASA-N

描述

應用

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

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其他說明

Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles

安全資訊

• 象形圖: GHS06,GHS08,GHS09
• 訊號詞: Danger
• 危險聲明: H301,H312,H315,H319,H360FD,H372,H410
• 防範說明: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
• 危險分類: Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
• 儲存類別代碼: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable