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重要文件

733350

Sigma-Aldrich

双[2-(2-溴异丁氧基)十一烷基]二硫化物

97%

同義詞:

11,11'-二硫代二[1-(2-溴-2-甲基丙酰氧基)十一烷], DTBU

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About This Item

經驗公式(希爾表示法):
C30H56Br2O4S2
CAS號碼:
分子量::
704.70
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23
暫時無法取得訂價和供貨情況

化驗

97%

形狀

solid

溶解度

1.500 at 20 °C

密度

1.177 g/mL at 25 °C

SMILES 字串

CC(C)(Br)C(=O)OCCCCCCCCCCCSSCCCCCCCCCCCOC(=O)C(C)(C)Br

InChI

1S/C30H56Br2O4S2/c1-29(2,31)27(33)35-23-19-15-11-7-5-9-13-17-21-25-37-38-26-22-18-14-10-6-8-12-16-20-24-36-28(34)30(3,4)32/h5-26H2,1-4H3

InChI 密鑰

IEGYEGYUHSQEAZ-UHFFFAOYSA-N

應用

原子转移自由基聚合(ATRP)引发剂,通常用于功能化贵金属表面,并用于制备聚合物刷和可生物降解的水凝胶。也可用于将温度和光敏感的可裂解区域引入聚合物中。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Shuai Zhao et al.
Proceedings of the National Academy of Sciences of the United States of America, 114(35), E7245-E7254 (2017-08-16)
Chemical modifications on histones and DNA/RNA constitute a fundamental mechanism for epigenetic regulation. These modifications often function as docking marks to recruit or stabilize cognate "reader" proteins. So far, a platform for quantitative and high-throughput profiling of the epigenetic interactome
Rui Yatabe et al.
Sensors (Basel, Switzerland), 13(7), 9294-9304 (2013-07-24)
In this study, we modified a surface plasmon resonance immunosensor chip with a polymer using surface-initiated atom transfer polymerization (SI-ATRP) for the highly sensitive detection of 2,4,6-trinitrotoluene (TNT). To immobilize a TNT analogue on the polymer, mono-2-(methacryloyloxy)ethylsuccinate (MES), which has

文章

查找如何利用原子转移自由基聚合(ATRP)工具合成明确的官能化聚合物。

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

條款

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

華威大學 Dave Haddleton 教授研究小組展示的 ATRP 聚合程序。

Questions

  1. Can the disulfide initiator be immobilized on the surface of pure Pt? The product description indicates that it can be used to "functionalize noble metal surfaces," with gold being a typical example. Will this process also work for Pt?

    1 answer
    1. Pt is utilized in ATRP (Atom Transfer Radical Polymerization) applications.

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