推薦產品
化驗
≥97% (AT)
形狀
lumps
反應適用性
core: nickel
reagent type: catalyst
SMILES 字串
CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C
InChI
1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1
InChI 密鑰
IRLHVNUEEKJBEL-UHFFFAOYSA-M
應用
Catalyst for:
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
- Alkyl-alkyl Kumada coupling of secondary alkyl halides
- Direct alkylation of heterocyclic C-H bonds
- Sonogashira coupling of nonactivated alkyl halides
- Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation
包裝
Bottomless glass bottle. Contents are inside inserted fused cone.
相關產品
產品號碼
描述
訂價
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
從最近期的版本中選擇一個：
分析證明 (COA)
Lot/Batch Number
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Oleg Vechorkin et al.
Angewandte Chemie (International ed. in English), 48(16), 2937-2940 (2009-01-29)
Reacting in the 'Ni'ck of time: The title reaction is realized by using an isolated Ni(II) complex (1). The catalysis tolerates a wide range of important functional groups that are often incompatible with Grignard reagents in cross-coupling reactions.
Zsolt Csok et al.
Journal of the American Chemical Society, 130(26), 8156-8157 (2008-06-06)
A new pincer-type bis(amino)amine (NN2) ligand and its lithium and nickel complexes, including Ni(II) methyl, ethyl, and phenyl complexes, were synthesized. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C-C coupled products and Ni(II) halides.
文章
鎳複合物可催化各種合成反應，如氧化加成、C-H 活化和交叉耦合。
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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