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Sigma-Aldrich

[1,3-双(二苯基膦)丙烷]二氯化镍(II)

同義詞:

(1,3-dppp)NiCl2, 1,3-双(二苯基膦)丙烷氯化镍(II), 镍 (dppp) Cl2

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About This Item

線性公式:
[(C6H5)2P(CH2)3P(C6H5)2]NiCl2
CAS號碼:
15629-92-2
分子量：:
542.04
MDL號碼:
MFCD00015318
分類程式碼代碼:
12161600
PubChem物質ID:
24860309
NACRES:
NA.22
暫時無法取得訂價和供貨情況

形狀

powder

品質等級

100

反應適用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

213 °C (dec.) (lit.)

SMILES 字串

Cl[Ni]Cl.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI

1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2

InChI 密鑰

ZBQUMMFUJLOTQC-UHFFFAOYSA-L

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相關類別

應用

[1,3-双(二苯基膦)丙烷]二氯化镍(II)可作为金属富勒烯配合物还原法合成的前体。[1]
以下过程的催化剂：
  • 嵌段共聚噻吩的合成
  • 卤代芳烃与芳基硼酸的 Suzuki-Miyaura 交叉偶联反应
  • 固态复缩聚反应
  • 聚（3-烷氧基噻吩）的聚合
  • 大环内酯类抗生素 aplyronine A 的 C1-C19 非对映选择性 Nozaki-Hiyama-Kishi 偶联反应
  • 共轭聚合物的转移缩聚

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象形圖

Health hazardExclamation mark
GHS08,GHS07

訊號詞

Danger

危險分類

Carc. 1A - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
MKCT5778
MKCN8457
0000094470
MKCL7329
0000071214

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The ?2 Complex of Nickel Bis (diphenylphosphanyl) propane with Fullerene
Konarev DV, et al.
European Journal of Inorganic Chemistry, 2011(6), 816-820 (2011)
Renxuan Xie et al.
Nature communications, 11(1), 893-893 (2020-02-16)
The glass transition temperature (Tg) is a key property that dictates the applicability of conjugated polymers. The Tg demarks the transition into a brittle glassy state, making its accurate prediction for conjugated polymers crucial for the design of soft, stretchable
Verónica Fernández-Stefanuto et al.
Frontiers in chemistry, 8, 208-208 (2020-04-09)
Surfactants have a great number of applications. Among these chemicals, petroleum sulfonates have been widely used due to their effectiveness in reducing interfacial tension. This is the case of sodium octylnaphthalene sulfonate which is a solid with a very low
Xiaoyu Li et al.
Nature communications, 8, 15909-15909 (2017-06-27)
Micelles formed by the self-assembly of block copolymers in selective solvents have attracted widespread attention and have uses in a wide variety of fields, whereas applications based on their electronic properties are virtually unexplored. Herein we describe studies of solution-processable
Kinga Kepska et al.
Chemicke zvesti, 72(1), 251-259 (2018-01-26)
The first comprehensive spectroelectrochemical account of the behaviour of regioregular (RR-P3HT) and statistical (ST-P3HT) poly(3-hexylthiophenes) in solution is presented, in contrast to the many reports dealing with P3HT films merely deposited from solution. The conducted experiments revealed that the two
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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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