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Merck
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重要文件

703788

Sigma-Aldrich

醇钠

99.9%

同義詞:

Sodium 2-methylpropan-2-olate, Sodium t-butoxide, Sodium tert-butanolate, Sodium tert-butylate

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About This Item

線性公式:
NaOC(CH3)3
CAS號碼:
分子量::
96.10
Beilstein:
3654215
EC號碼:
MDL號碼:
分類程式碼代碼:
12352107
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

99.9%

形狀

powder

密度

1.025  g/cm3 at 68 °F

SMILES 字串

[Na+].CC(C)(C)[O-]
[Na+].CC(C)(C)[O-]

InChI

1S/C4H9O.Na/c1-4(2,3)5;/h1-3H3;/q-1;+1
1S/C4H9O.Na/c1-4(2,3)5;/h1-3H3;/q-1;+1

InChI 密鑰

MFRIHAYPQRLWNB-UHFFFAOYSA-N
MFRIHAYPQRLWNB-UHFFFAOYSA-N

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應用

丁醇钠可用作:
  • 作为促进剂,促进芳香族化合物与卤代芳烃通过C-H键芳基化反应合成联芳基。[1]
  • 钯催化胺化反应中的碱。[2]
  • 作为碱,在钯催化剂存在的条件下,由未活化的芳基卤化物合成芳基 丁基醚。[3]
  • 参与 N-吲哚和 N-氮杂吲哚的去磺酰反应。[4]
  • 作为碱,用于烯烃和CO2合成丙烯酸钠。 [5]

象形圖

FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 1 - Skin Corr. 1B

安全危害

儲存類別代碼

4.2 - Pyrophoric and self-heating hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

57.2 °F

閃點(°C)

14 °C


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分析證明 (COA)

Lot/Batch Number

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存取文件庫

tert-Butoxide-Mediated C-H Bond Arylation of Aromatic Compounds with Haloarenes
Yanagisawa S and Itami K
ChemCatChem, 3(5), 827-829 (2011)
Desulfonylation of Indoles and 7-Azaindoles Using Sodium tert-Butoxide
Chaulet C, et al.
Synlett, 2010(10), 1481-1484 (2010)
Synthesis of acrylates from olefins and CO2 using sodium alkoxides as bases
Manzini S, et al.
Catalysis Today, 281(10), 379-386 (2017)
β-Hydrogen-Containing Sodium Alkoxides as Suitable Bases in Palladium-Catalyzed Aminations of Aryl Halides
Prashad M, et al.
The Journal of Organic Chemistry, 65(8), 2612-2614 (2000)
Palladium-catalyzed formation of aryl tert-butyl ethers from unactivated aryl halides
Parrish CA and Buchwald SL
The Journal of Organic Chemistry, 66(7), 2498-2500 (2001)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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