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Merck
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重要文件

698717

Sigma-Aldrich

聚氧乙基-α-生育酚癸二酸酯

greener alternative

15 wt. % in H2O

同義詞:

PTS

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About This Item

CAS號碼:
MDL號碼:
分類程式碼代碼:
12162002
NACRES:
NA.22
暫時無法取得訂價和供貨情況

形狀

liquid

分子量

~1,200

反應適用性

reaction type: C-C Bond Formation

環保替代產品特色

Waste Prevention
Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

濃度

15 wt. % in H2O

環保替代類別

一般說明

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced to increase the catalytic efficiency and acts as an environmentally benign and sustainable amphiphile. Click here for more information.

應用

PTS: Amphiphile for Organic Synthesis in Water

Uses:
  • Provides an aqueous micellar environment for transition metal-catalyzed Heck coupling, cross metathesis and ring closing metathesis reactions
  • Surfactant for catalytic asymmetric Baeyer-Villiger oxidation in water using PtII catalysts and hydrogen peroxide
  • Orally active CoQ10 carrier for neuroprotection after stroke or cardiac arrest

法律資訊

Zymes LLC 的产品,经美国和世界专利及待审专利独家授权销售。

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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分析證明 (COA)

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文章

Micellular catalysis has provided the ability to carry out several commonly used transformations used in the synthetic community to be carried out in water.

Surfactants for efficient reactions in water as a green chemistry alternative.

Baeyer-Villiger 氧化作用是氧化裂解與羰基相鄰的碳-碳鍵,將酮類轉換為酯類,環酮類轉換為內酯類。

The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.

相關內容

Micellular catalysis has provided the ability to carry out several commonly used transformations used in the synthetic community to be carried out in water.

Designer surfactants enable diverse transformations like Suzuki-Miyaura, Olefin Metathesis, and 1,4-Addition to Enones in water by Prof. Bruce Lipshutz.

Questions

1–2 of 2 Questions  
  1. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  2. What can Product 698717, Polyoxyethanyl-α-tocopheryl sebacate, be used for?

    1 answer
    1. PTS is a non-ionic amphiphile that can be used to "solubilize" organic molecules in aqueous media. The PTS molecule forms micelles around the lipophilic compounds, allowing them to move into the aqueous phase for effective cross-coupling and metathesis reactions without the need of a co-solvent.

      Helpful?

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