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重要文件

687952

Sigma-Aldrich

(环己基甲基)溴化镁

同義詞:

Cyclohexylmethylmagnesium bromide

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About This Item

經驗公式(希爾表示法):
C7H13BrMg
CAS號碼:
分子量::
201.39
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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品質等級

形狀

liquid

反應適用性

reaction type: Grignard Reaction

密度

0.966 g/mL at 25 °C

SMILES 字串

Br[Mg]CC1CCCCC1

InChI

1S/C7H13.BrH.Mg/c1-7-5-3-2-4-6-7;;/h7H,1-6H2;1H;/q;;+1/p-1

InChI 密鑰

ZBCIOGFGZRNNEC-UHFFFAOYSA-M

應用

Reactant involved in:
  • Isomerization polymerization of alkenylcyclohexanes
  • Intramolecular rearrangements of vinylidenecyclopropanes
  • Cycloisomerization of cyclic and acyclic enynes

Additionally reactant involved in synthesis of biologically active molecules including:
  • Dipeptidyl boronic acid proteasome inhibitors
  • Substituted 1,3-dihydroindole-2-ones with antitumor effects
  • Sulfur-free transition state nucleoside analog inhibitors of methylthioadenosine nucleosidase and phosphorylase

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

-4.0 °F

閃點(°C)

-20 °C


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分析證明 (COA)

Lot/Batch Number

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Questions

  1. What solution is this in (ie: THF)? What is the concentration (ie: 0.2M, 1M, 2M...)?

    1 answer
    1. The concentration of this product ranges from 0.40 - 0.60 M in THF. The exact concentration is listed on the lot-specific Certificate of Analysis. Please see the sample Certificate of Analysis: https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/687952-50ML0000235108.pdf

      Please see the link below to the SDS which lists each component in Section 3:
      https://www.sigmaaldrich.com/sds/aldrich/687952

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