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682500

Sigma-Aldrich

噻吩-2-甲酸亚铜

同義詞:

2-噻吩甲酸，铜络合物, 2-噻吩羧酸亚铜, Cu(TC), （2-噻吩甲氧基）铜

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About This Item

經驗公式（希爾表示法）:
C5H3CuO2S
CAS號碼:
68986-76-5
分子量：:
190.69
MDL號碼:
MFCD02183524
分類程式碼代碼:
12161600
PubChem物質ID:
24885718
NACRES:
NA.22
暫時無法取得訂價和供貨情況

形狀

solid

品質等級

100

反應適用性

core: copper
reaction type: C-C Bond Formation
reagent type: catalyst

SMILES 字串

[Cu]OC(=O)c1cccs1

InChI

1S/C5H4O2S.Cu/c6-5(7)4-2-1-3-8-4;/h1-3H,(H,6,7);/q;+1/p-1

InChI 密鑰

SFJMFSWCBVEHBA-UHFFFAOYSA-M

相關類別

應用

可作为以下过程的反应物或试剂：
  • 对除草剂安全剂衍生物的异生物反应的研究
  • 功能化BODIPY染料类似物的合成
  • 正交交叉偶联反应
  • 母体硼二吡咯甲烷体系的制备
  • 铜介导的交叉耦合
铜（I）噻吩-2-羧酸酯在下列过程中可用作反应物或试剂：
  • 对除草剂安全剂衍生物的异生物反应的研究。[1]
  • 功能化BODIPY染料类似物的合成。[2]
  • 正交交叉偶联反应。[3]
  • 母体硼二吡咯甲烷体系的制备。[4]
  • 铜介导的交叉耦合。[5][6]

象形圖

Environment
GHS09

訊號詞

Warning

危險聲明

H410

防範說明

P273 - P391 - P501

危險分類

Aquatic Acute 1 - Aquatic Chronic 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
MKCP0766
MKCQ5564
MKCJ9381
MKCD4033
MKBX2582V

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存取文件庫

Xenobiotic responsiveness of Arabidopsis thaliana to a chemical series derived from a herbicide safener.
Skipsey M, et al.
The Journal of Biological Chemistry, 286(37), 32268-32276 (2011)
The smallest and one of the brightest. Efficient preparation and optical description of the parent borondipyrromethene system.
Arroyo I J, et al.
The Journal of Organic Chemistry, 74(15), 5719-5722 (2009)
N-Amidation by copper-mediated cross-coupling of organostannanes or boronic acids with O-acetyl hydroxamic acids.
Zhang Z, et al.
Organic Letters, 10(14), 3005-3008 (2008)
Regioselective Syntheses of 2, 3?Substituted Pyridines by Orthogonal Cross?Coupling Strategies.
Koley M, et al.
European Journal of Organic Chemistry, 2011(10), 1972-1979 (2011)
2?and 3?Monohalogenated BODIPY Dyes and Their Functionalized Analogues: Synthesis and Spectroscopy.
Leen V, et al.
European Journal of Organic Chemistry, 2011(23), 4386-4396 (2011)
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Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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