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重要文件

677264

Sigma-Aldrich

APhos

95%

同義詞:

(4-(N,N-二甲氨基)苯基)二-叔丁基膦, A-taPhos, [4-(二甲氨基)苯基]双(叔丁基)苯基

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About This Item

經驗公式(希爾表示法):
C16H28NP
CAS號碼:
分子量::
265.37
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22
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化驗

95%

形狀

solid

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reagent type: ligand
reaction type: Cross Couplings

mp

57-61 °C

官能基

phosphine

SMILES 字串

CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C

InChI

1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3

InChI 密鑰

IQTHEAQKKVAXGV-UHFFFAOYSA-N

應用

用于制备处理 PdCl2 (COD) 所用的二氯化钯催化剂 (678740) 的配体。该催化剂使芳基硼酸与杂芳基氯化物高效交联。[1]

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8B - Non-combustible, corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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分析證明 (COA)

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Anil S Guram et al.
Organic letters, 8(9), 1787-1789 (2006-04-21)
[reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions of aryl halides including five-membered heteroaryl halides and heteroatom-substituted six-membered heteroaryl chlorides with a diverse range of

文章

Ligand used to prepare a palladium dichloride catalyst on treatment with PdCl2(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.

相關內容

The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.

Catalexis 平台透過數位方式優化催化劑的選擇,以找出最有效的膦配位體來進行交叉耦合反應,從而增強催化作用。

Catalexis 平台透過數位方式優化催化劑的選擇,以找出最有效的膦配位體來進行交叉耦合反應,從而增強催化作用。

Explore reliable, premium grade catalysis materials for your pharma or industrial project. Specialty chemicals and formulations are available in bulk quantities and volumes from a few grams to multi-metric tons with complete documentation to simplify your leap from development to commercialization.

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