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Sigma-Aldrich

2,4-二硝基苯磺酸 水合物

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About This Item

線性公式:
(O2N)2C6H3SO3H · xH2O
CAS號碼:
698999-22-3
分子量：:
248.17 (anhydrous basis)
MDL號碼:
MFCD00066017
分類程式碼代碼:
12352100
PubChem物質ID:
24879598
NACRES:
NA.22
暫時無法取得訂價和供貨情況

mp

95-98 °C (lit.)

官能基

nitro
sulfonic acid

SMILES 字串

OS(=O)(=O)c1ccc(cc1[N+]([O-])=O)[N+]([O-])=O

InChI

1S/C6H4N2O7S/c9-7(10)4-1-2-6(16(13,14)15)5(3-4)8(11)12/h1-3H,(H,13,14,15)

InChI 密鑰

OVOJUAKDTOOXRF-UHFFFAOYSA-N

應用

2,4-二硝基苯磺酸水合物可用于合成相应的 α--羟酮。它可用作酰胺化反应的催化剂，该反应涉及二元醇转化为 N -苄基乙酰胺。[1]它也可用于制备 1-辛基-2-吡咯烷酮-2,4-二硝基苯磺酸盐 ([NOP][DNBSA])，一种 Brønsted-酸性离子液体，可催化三恶烷的合成。[2]

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

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分析證明 (COA)

Lot/Batch Number
MKCM8197
MKCQ7618
MKCQ2262
MKCN6225
STBH2928

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"Bronsted-Acidic Ionic Liquids as Catalysts for Synthesizing Trioxane"
Zhao Y, et al.
Chinese Journal of Chemical Engineering (2016)
"The Ritter reaction under truly catalytic Bronsted acid conditions"
Sanz R, et al.
European Journal of Organic Chemistry, 2007(08), 4642-4645 (2007)
Yejin Yang et al.
Drug design, development and therapy, 13, 231-242 (2019-01-16)
We examined whether metoclopramide (MCP), a modulator of dopamine and serotonin receptors, alleviated colitis and had synergistic effects when coadministered with 5-aminosalicylic acid (5-ASA) in an experimental model of colitis. MCP azo-linked to 5-ASA (5-[4-chloro-2-{2-(diethylamino)ethylcarbamoyl}- 1-methoxyphenyl]azosalicylic acid, MCP-azo-ASA) was synthesized
Shurong Ren et al.
International immunopharmacology, 72, 284-291 (2019-04-21)
Imiquimod (Imiq) is a synthetic imizoquinoline compound which can act on Toll-like receptor (TLR)7 and transduce signals involved in cell activation. We investigated the role of Imiq on contact hypersensitivity (CHS) and explored the potential mechanisms of mast cells involved
Tatsuya Ogawa et al.
Journal of immunology (Baltimore, Md. : 1950), 205(4), 907-914 (2020-07-22)
Atopic dermatitis is a chronic form of allergic contact dermatitis that is closely associated with a compromised epidermal barrier. Immunogenicity of a given electrophilic hapten after penetration of this barrier depends directly on biochemical reactions in the thiol-rich layer in

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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