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469858

Sigma-Aldrich

四(二甲基胺基)钛(IV)

99.999% trace metals basis

同義詞:

TDMAT, 四(二甲基氨基)钛(IV)

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About This Item

線性公式:
[(CH3)2N]4Ti
CAS號碼:
分子量::
224.17
EC號碼:
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23
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品質等級

化驗

99.999% trace metals basis

形狀

liquid

反應適用性

core: titanium

bp

50 °C/0.5 mmHg (lit.)

密度

0.947 g/mL at 25 °C (lit.)

SMILES 字串

CN(C)[Ti](N(C)C)(N(C)C)N(C)C

InChI

1S/4C2H6N.Ti/c4*1-3-2;/h4*1-2H3;/q4*-1;+4

InChI 密鑰

MNWRORMXBIWXCI-UHFFFAOYSA-N

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應用

Tetrakis(二甲基氨基)钛(IV)(TDMAT)是通过有机金属化学气相沉积(OMCVD)[1]和通过原子层沉积(ALD)的二氧化钛薄膜的氮化钛(TiN)薄膜的前体。[2][3][4]TDMAT 与过量的环戊二烯发生放热反应得到三(二甲基氨基)(η5-环戊二烯基)钛(IV)。[5]

象形圖

FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

安全危害

儲存類別代碼

4.3 - Hazardous materials which set free flammable gases upon contact with water

水污染物質分類(WGK)

WGK 3

閃點(°F)

-22.0 °F - closed cup

閃點(°C)

-30 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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文章

Titanium dioxide applications: Semiconducting material characteristics and diverse functionalities.

二氧化鈦的應用:半導體材料特性與多樣化功能。

Continuous efficiency improvements in photovoltaic devices result from material advancements and manufacturing innovation.

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What sealing procedure was used for the ampule containing 469858-5G? There were issues when attempting to reseal the ampule using parafilm. Therefore, a resealing procedure is needed to ensure that the contents can be used over time without crystallizing.

    1 answer
    1. The ampules are intended for one-time use only. For any remaining material, it is advised to transfer it to a bottle with a screw cap in a glove bag under inert atmosphere instead of trying to re-seal the glass ampule. It's important to note that this material is highly sensitive to air and water, so it cannot be guaranteed that the material will not degrade once the ampule has been opened and the contents transferred to a new bottle.

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