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重要文件

446130

Sigma-Aldrich

3-[三(三甲基硅氧基)硅烷基] 甲基丙烯酸丙酯

contains MEHQ + HQ as stabilizer, 98%

同義詞:

Tris, 甲基丙烯酰氧丙基三(三甲基硅氧烷基)硅烷

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About This Item

線性公式:
H2C=C(CH3)CO2(CH2)3Si[OSi(CH3)3]3
CAS號碼:
分子量::
422.81
Beilstein:
1888727
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23
暫時無法取得訂價和供貨情況

蒸汽壓力

<1 mmHg ( 20 °C)

化驗

98%

形狀

liquid

包含

MEHQ + HQ as stabilizer

折射率

n20/D 1.419 (lit.)

bp

112-115 °C/0.2 mmHg (lit.)

密度

0.918 g/mL at 25 °C (lit.)

SMILES 字串

CC(=C)C(=O)OCCC[Si](O[Si](C)(C)C)(O[Si](C)(C)C)O[Si](C)(C)C

InChI

1S/C16H38O5Si4/c1-15(2)16(17)18-13-12-14-25(19-22(3,4)5,20-23(6,7)8)21-24(9,10)11/h1,12-14H2,2-11H3

InChI 密鑰

BESKSSIEODQWBP-UHFFFAOYSA-N

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一般說明

3-[Tris(trimethylsiloxy)silyl]propyl methacrylate (TMSPM) is a silane-modified methacrylate characterized by its unique siloxy functional groups, which impart hydrophobicity and thermal stability. This compound serves as a versatile monomer in polymer synthesis, enabling the formation of siloxane-containing polymers with enhanced mechanical properties. Its excellent adhesion properties make it suitable for use in coatings, adhesives, and sealants.

應用

3-[Tris(trimethylsiloxy)silyl]propyl methacrylate can be used:
  • As a silicone containing monomer to synthesize hydrogels for Opthalmic medical devices such as contact lenses with enhanced mechanical properties. Addition of TMSPM increases the oxygen permeability of the contact lens without affecting light transmission.
  • As a precursor to fabricate dissolved oxygen sensor by embedding a highly stable and highly hydrophobic fluorinated matrix via free radical polymerization.
  • To fabricate bio-based polymers for anti-stain and oil resistant textile coatings. The addition of TMSPM significantly enhances the oil repellence property of the coating.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

393.8 °F - closed cup

閃點(°C)

201 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Furqan A Maulvi et al.
Acta biomaterialia, 86, 350-362 (2019-01-10)
Contact lenses are ideally suited for extended drug delivery to the ocular tissues, but incorporation of any particulate system affects the critical properties of the contact lens. Timolol loading by the conventional soaking method does not significantly alter the critical
Hsiu-Wen Chien et al.
Journal of biomaterials science. Polymer edition, 30(12), 1050-1067 (2019-05-21)
The present work proposes to investigate two series of silicone hydrogel materials for their characterization, water content, surface wettability, transmittance, mechanical property, oxygen permeability (Dk), and bacterial attachment as potential contact lens materials and discuss the relationships between water affinity
Furqan A Maulvi et al.
International journal of pharmaceutics, 566, 513-519 (2019-06-09)
The optical and swelling properties of gatifloxacin-loaded contact lens decrease owing to the precipitation of gatifloxacin (on hydration) in the matrix structure of the contact lens. This paper focuses on the use of Pluronic F68 both inside and outside (in
Ankita R Desai et al.
Materials science & engineering. C, Materials for biological applications, 112, 110885-110885 (2020-05-16)
A fixed combination of bimatoprost/timolol eye drop solution is used to manage the elevated intra-ocular pressure in glaucoma patients, including individuals whose condition is poorly controlled by monotherapy. Eye drop solutions are generally given in high dose, due to poor
Nguyen-Phuong-Dung Tran et al.
Polymers, 11(6) (2019-06-05)
In this study, silicone-based hydrogel contact lenses were prepared by the polymerization of 3-(methacryloyloxy)propyltris(trimethylsiloxy)silane (TRIS), N,N-dimethylacrylamide (DMA), 1-vinyl-2-pyrrolidinone (NVP), and 2-hydroxyethylmethacrylate (HEMA). The properties of silicone hydrogel lenses were analyzed based on the methods such as equilibrium water content, oxygen

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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