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重要文件

349585

Sigma-Aldrich

苯甲酰二茂铁

≥98%

同義詞:

苯甲酰基二茂铁

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About This Item

經驗公式(希爾表示法):
C17H14FeO
CAS號碼:
分子量::
290.14
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.22

化驗

≥98%

反應適用性

core: iron
reagent type: catalyst

mp

105-107 °C (lit.)

SMILES 字串

[Fe].[CH]1[CH][CH][CH][CH]1.O=C([C]2[CH][CH][CH][CH]2)c3ccccc3

InChI

1S/C12H9O.C5H5.Fe/c13-12(11-8-4-5-9-11)10-6-2-1-3-7-10;1-2-4-5-3-1;/h1-9H;1-5H;

InChI 密鑰

JJHHJZCYDPLHIL-UHFFFAOYSA-N

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應用

Reactant for:
  • Deprotonative metalation of ferrocenes
  • Oxidative chemistry
  • Reduction of ferrocenyl ketones
  • Polymerization of C-ferrocenyl-substituted phosphaalkene

Reactant for synthesis of:
  • Planat chiral triferrocenylmethane derivative
  • Chiral ferrocenyl alcohols via asymmetric transfer hydrogenation

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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分析證明 (COA)

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The addition polymerization of a ferrocenyl-substituted P[double bond]C bond leads to new redox-active polymers with functional ferrocene and phosphine moieties.
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A series of compounds is described in which one of the ethyl groups in diethylstilbestrol has been replaced by a ferrocenyl substituent. Only those derivatives incorporating phenol moieties underwent isomerisation from the Z to the E form, and some of
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A mixed lithium-cadmium amide and a combination of lithium and zinc amides were reacted with a range of ferrocenes; deprotonative mono- or dimetallation in general occurred chemoselectively at room temperature, as evidenced by subsequent quenching with iodine.
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