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F408

Sigma-Aldrich

二茂铁

98%

同義詞:

二环戊二烯铁, 双环戊二烯基铁

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About This Item

線性公式:
Fe(C5H5)2
CAS號碼:
102-54-5
分子量：:
186.03
EC號碼:
203-039-3
MDL號碼:
MFCD00001427
分類程式碼代碼:
12161600
PubChem物質ID:
24894802
NACRES:
NA.22
暫時無法取得訂價和供貨情況

蒸汽壓力

0.03 mmHg ( 40 °C)

品質等級

100

化驗

98%

反應適用性

core: iron
reagent type: catalyst

bp

249 °C (lit.)

mp

172-174 °C (lit.)

λmax

358 nm

儲存溫度

2-8°C

SMILES 字串

[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;

InChI 密鑰

DFRHTHSZMBROSH-UHFFFAOYSA-N

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相關類別

應用

二茂铁（二环戊二烯基铁）可用于：
  • 用作不对称催化中的手性配体支架。[1]
  • 染料敏化太阳能电池应用中的二茂铁基电解质。[2]
  • 合成不对称二茂铁配体，可用作交叉偶联、氢化、烯丙基取代的催化剂。[3]
  • 通过化学气相沉积法合成二维六方有序介孔碳（CMK-5），用作甲醇氧化的催化剂载体。[4]
  • 合成二茂铁与富勒烯的分子杂化物（巴基二茂铁）。[5]
  • 制备二茂铁盐，用作温和氧化剂。[6]

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation

標靶器官

Liver

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類（WGK）

WGK 2

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

從最近期的版本中選擇一個：

分析證明 (COA)

Lot/Batch Number
STBL3617
SDBB0410
STBL2804
STBL3168
STBL1710

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Lanti Yang et al.
Journal of the American Chemical Society, 134(46), 19199-19206 (2012-11-07)
Adopting supramolecular chemistry for immobilization of proteins is an attractive strategy that entails reversibility and responsiveness to stimuli. The reversible and oriented immobilization and micropatterning of ferrocene-tagged yellow fluorescent proteins (Fc-YFPs) onto β-cyclodextrin (βCD) molecular printboards was characterized using surface
Micheál D Scanlon et al.
Physical chemistry chemical physics : PCCP, 15(8), 2847-2857 (2013-01-23)
Rarely reported low-cost molybdenum boride and carbide microparticles, both of which are available in abundant quantities due to their widespread use in industry, adsorb at aqueous acid-1,2-dichloroethane interfaces and efficiently catalyse the hydrogen evolution reaction in the presence of the
CMK-5 mesoporous carbon synthesized via chemical vapor deposition of ferrocene as catalyst support for methanol oxidation
Lei Z, et al.
The Journal of Physical Chemistry C, 3(112), 722-731 (2008)
Asymmetric catalysis with chiral ferrocene ligands
Dai LX, et al.
Accounts of Chemical Research, 36(9), 659-667 (2003)
Muneebah Adams et al.
Dalton transactions (Cambridge, England : 2003), 42(13), 4677-4685 (2013-01-31)
A series of aryl-functionalized and ferrocenyl monothiosemicarbazone compounds (L1-L4) were synthesized in moderate yields via a general Schiff-base condensation reaction. The thiosemicarbazone (TSC) ligands were reacted with the ruthenium dimer [Ru(Ar)(μ-Cl)Cl](2) (Ar = benzene; p-cymene) to yield a series of
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文章

Molecular Layer Deposition of Polymers

Atomic layer deposition meets various needs including semiconductor device miniaturization and nanoparticle coating.

聚合物的分子層沉積

原子層沉積可滿足各種需求，包括半導體裝置微型化及奈米塗層。

Questions

1–3 of 3 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. What is the thermal stability of the product ferrocene (F408) and what is the temperature limit for ferrocene before it decomposes into different elements or chemicals?

    1 answer

    1. Decomposition temperature has not been tested for the product ferrocene (F408). Please refer to the following article for more information; J. Phys. Chem. B 2006, 110, 42, 20973–20977. Publication Date:September 29, 2006. https://doi.org/10.1021/jp0636571

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