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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
About This Item
推薦產品
品質等級
化驗
98%
形狀
solid
反應適用性
core: palladium
reaction type: Cross Couplings
reagent type: catalyst
reaction type: C-H Activation
環保替代產品特色
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
環保替代類別
, Aligned
儲存溫度
2-8°C
SMILES 字串
Cl[Pd]CC=C.Cl[Pd]CC=C
InChI
1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
InChI 密鑰
TWKVUTXHANJYGH-UHFFFAOYSA-L
尋找類似的產品？ 前往 產品比較指南
一般說明
應用
- 微波辅助Heck芳基化用阳离子钯催化剂的合成。[2]
- N-杂环卡宾-钯-η3-烯丙基氯络合物的合成：它是芳基溴化物和活化芳基氯化物Suzuki-Miyaura交叉偶联的有效催化剂。[3]
- 1，4-二烯丙基-1，2-二氢异喹啉的合成。[4]
- 作为TPGS-750-M更绿色Buchwald-Hartwig耦合的催化剂
朝着通过E因子而量化的绿色过渡金属催化过程前进
訊號詞
Warning
危險聲明
危險分類
Skin Irrit. 2
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
個人防護裝備
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
從最近期的版本中選擇一個：
分析證明 (COA)
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文章
A variety of palladium-catalyzed cross-coupling reactions can be run under room temperature conditions in water with TPGS- 750-M, using a variety of commercially available palladium complexes and ligands.
Heck反应是烯烃与芳基或乙烯基卤化物（或三氟甲磺酸酯）之间的钯催化交叉偶联反应，用于生成取代的烯烃。
條款
TPGS-750-M surfactant enables various reactions in water at room temperature, enhancing efficiency and versatility in synthesis.
TPGS-750-M 表面活化劑可在室溫下於水中進行各種反應，提高合成的效率與多樣性。
相關內容
TPGS-750-M, a second generation surfactant, may be used in the Buchwald-Hartwig Amination Reaction in Water at Room Temperature.
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How is shipping temperature determined? And how is it related to the product storage temperature?
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How can I determine the shelf life / expiration / retest date of this product?
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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