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186317

Sigma-Aldrich

N,N-二乙基甲酰胺

99%

同義詞:

N-甲酰二乙胺

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About This Item

線性公式:
HCON(C2H5)2
CAS號碼:
分子量::
101.15
Beilstein:
1209392
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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品質等級

化驗

99%

形狀

liquid

折射率

n20/D 1.434 (lit.)

bp

176-177 °C (lit.)

密度

0.908 g/mL at 25 °C (lit.)

官能基

amide

SMILES 字串

CCN(CC)C=O

InChI

1S/C5H11NO/c1-3-6(4-2)5-7/h5H,3-4H2,1-2H3

InChI 密鑰

SUAKHGWARZSWIH-UHFFFAOYSA-N

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一般說明

N,N'-二乙基甲酰胺在密封的反应器中在 ZnCl2存在下与芳族o-氨基腈缩合,得到喹唑啉-2,4(1H,3H) - 二酮[1]

應用

N,N -二乙基甲酰胺用于合成金属-有机骨架 [2]。它也被用来作为溶剂合成多孔立方形氧化锌颗粒 [3]

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

水污染物質分類(WGK)

WGK 1

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析證明 (COA)

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Yu Kimitsuka et al.
Inorganic chemistry, 52(24), 14028-14033 (2013-11-26)
A method for synthesizing porous cubic-shaped ZnO particles a few tens of micrometers in size is described on the basis of a pyrolytic conversion of Zn-terephthalate metal-organic frameworks (MOFs). MOF crystals were initially grown in solutions containing Zn(NO3)2·6H2O and terephthalic
Yuxia Shen et al.
Advanced materials (Deerfield Beach, Fla.), 30(52), e1802497-e1802497 (2018-11-06)
Large-scale synthesis of van der Waals (vdW) metal-organic framework (MOF) nanosheets with controlled crystallinity and interlayer coupling strength is one of the bottlenecks in 2D materials that has limited its successful transition to large-scale applications. Here, scalable synthesis of mBDC
Yingmu Zhang et al.
Dalton transactions (Cambridge, England : 2003), 47(34), 11806-11811 (2018-06-05)
A new luminescent mesoporous metal-organic framework (PCN-604) was successfully synthesized from trimetric clusters, Al3(O)(CH3COO)6, and pyridine-based tritopic linkers, 4,4',4''-(pyridine-2,4,6-triyl)tribenzoate (PTB), via a solvothermal reaction. The MOF with an MTN topology possesses remarkable aqueous and thermal stabilities. Due to the efficient
South African research into AIDS "cure" severely criticised.
P Sidley
BMJ (Clinical research ed.), 314(7083), 771-771 (1997-03-15)
Jiarong Li et al.
Organic letters, 11(6), 1193-1196 (2009-02-26)
A new and facile preparation of quinazoline-2,4(1H,3H)-diones was first reported which was the condensation of aromatic o-aminonitriles with DMF or N,N-diethylformamide in the presence of ZnCl(2) (0.5-10 mol %) at 190-200 degrees C in the sealed reactor.

文章

金属有机骨架是配位聚合物的一部分,代表了大量替代能源应用的一个强大的新工具。通过提供定制的高表面积材料的简单的合成策略可以很容易获得MOF。

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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