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117854

Sigma-Aldrich

三正辛基膦

technical grade, 90%

同義詞:

TOP, P(Oct)3

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About This Item

線性公式:
[CH3(CH2)7]3P
CAS號碼:
分子量::
370.64
Beilstein:
1776995
EC號碼:
MDL號碼:
分類程式碼代碼:
12352001
PubChem物質ID:
NACRES:
NA.22
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等級

technical grade

化驗

90%

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

折射率

n20/D 1.468 (lit.)

bp

284-291 °C/50 mmHg (lit.)

密度

0.831 g/mL at 25 °C (lit.)

官能基

phosphine

SMILES 字串

CCCCCCCCP(CCCCCCCC)CCCCCCCC

InChI

1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3

InChI 密鑰

RMZAYIKUYWXQPB-UHFFFAOYSA-N

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應用

三辛基膦能将金属纳米晶体,大体积粉末,箔片,线状,薄膜转化为金属磷化物。[1]它还可用作硫和乙酸镉合成硫化镉纳米棒的溶剂和稳定剂。[2]

包裝

建议将25 mL Sure/Seal 瓶作为一次性瓶使用。 反复穿刺可能会导致产品性能下降。

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

296.6 °F - closed cup

閃點(°C)

147 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析證明 (COA)

Lot/Batch Number

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存取文件庫

Synthesis of cdses nanocrystals in coordinating and noncoordinating solvents: Solvent's role in evolution of the optical and structural properties.
Al-Salim N
Chemistry of Materials, 19(21), 5185-5193 (2007)
Synthesis and characterization of nearly monodisperse CdE (E= sulfur, selenium, tellurium) semiconductor nanocrystallites.
Murray C
Journal of the American Chemical Society, 115(19), 8706-8715 (1993)
Yuhuan Ji et al.
Analytical chemistry, 87(11), 5500-5504 (2015-05-07)
Bottom-up proteomics is a powerful tool for characterization of protein post-translational modifications (PTMs), where PTMs are identified at the peptide level by mass spectrometry (MS) following protein digestion. However, enzymatic digestion is associated with additional sample processing steps that may
Liam R Bradshaw et al.
Nano letters, 15(2), 1315-1323 (2015-01-15)
Luminescent solar concentrators (LSCs) harvest sunlight over large areas and concentrate this energy onto photovoltaics or for other uses by transporting photons through macroscopic waveguides. Although attractive for lowering solar energy costs, LSCs remain severely limited by luminophore reabsorption losses.
Neha Arora et al.
Physical chemistry chemical physics : PCCP, 16(23), 11381-11389 (2014-05-07)
Here we present digestive ripening facilitated interatomic diffusion for the phase controlled synthesis of homogeneous intermetallic nanocrystals of Au-Sn system. Au and Sn metal nanoparticles synthesized by a solvated metal atom dispersion (SMAD) method are employed as precursors for the

文章

溶剂热合成是一种制备材料的方法,例如金属、半导体、陶瓷和聚合物。

Solvothermal synthesis of nanoparticles: applications from nanocircuits and nano-optical circuits to nanomagnetics and biotech.

相關內容

The Catalexis platform enhances catalysis by digitally optimizing catalyst selection to identify the most effective phosphine ligands for cross-coupling reactions.

Catalexis 平台透過數位方式優化催化劑的選擇,以找出最有效的膦配位體來進行交叉耦合反應,從而增強催化作用。

Catalexis 平台透過數位方式優化催化劑的選擇,以找出最有效的膦配位體來進行交叉耦合反應,從而增強催化作用。

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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