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Merck

360716

Sigma-Aldrich

三(三甲基硅基)硅烷

97%

别名:

TTMSS, 三(三甲硅烷基)硅烷

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5 G
$204.00
25 G
$502.00

$204.00


预计发货时间2025年4月21日详情


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5 G
$204.00
25 G
$502.00

About This Item

线性分子式:
[(CH3)3Si]3SiH
CAS号:
分子量:
248.66
Beilstein:
1923953
MDL编号:
UNSPSC代码:
12161700
PubChem化学物质编号:
NACRES:
NA.22

$204.00


预计发货时间2025年4月21日详情


获取大包装报价

质量水平

方案

97%

表单

liquid

反应适用性

reagent type: reductant

折射率

n20/D 1.489 (lit.)

沸点

73 °C/5 mmHg (lit.)

密度

0.806 g/mL at 25 °C (lit.)

SMILES字符串

C[Si](C)(C)[SiH]([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C9H28Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h10H,1-9H3

InChI key

SQMFULTZZQBFBM-UHFFFAOYSA-N

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一般描述

三(三甲基硅基)硅烷是一种有机硅,通常作为自由基还原剂,用于黄原酸酯,有机卤化物,异氰化物,硒化物和酰基氯化物。也用于烯烃,炔烃和二烷基酮的硅氢加成。[1][2][3]

应用

超甲硅烷基保护基团

可用于:
  • 氢化硅烷化
  • 自由基反应
  • 酸性氯化物的还原
  • 碳-卤键的还原
  • 羰基氢化反应

  • 另一种常见应用涉及在与过渡金属和主族元素络合时,三(三甲基甲硅烷基)甲硅烷基(TTMSS或超甲硅烷基)基团的使用

  • 最近,超甲硅烷基被用于碳-碳键形成的反应

象形图

Flame

警示用语:

Warning

危险声明

预防措施声明

危险分类

Flam. Liq. 3

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

131.0 °F - closed cup

闪点(°C)

55 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Tris(trimethylsilyl)silane
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2007)
Accounts of Chemical Research, 25, 188-188 (1992)
Tris (trimethylsilyl) silane. A new reducing agent
Chatgilialoglu C, et al.
The Journal of Organic Chemistry, 53(15), 3641-3642 (1988)
Synlett, 91-91 (1990)
Tris (trimethylsilyl) silane: an efficient hydrosilylating agent of alkenes and alkynes
Kopping B, et al.
The Journal of Organic Chemistry, 57(14), 3994-4000 (1992)

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  1. How can I determine the shelf life / expiration / retest date of this product?

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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