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Merck

92361

Sigma-Aldrich

三甲基氯硅烷

≥98.0% (GC)

别名:

TMCS, Trimethylchlorosilane, 三甲基硅基氯

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About This Item

线性分子式:
(CH3)3SiCl
CAS号:
分子量:
108.64
Beilstein:
1209232
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3.7 (vs air)

品質等級

蒸汽壓力

100 mmHg ( 25 °C)

化驗

≥98.0% (GC)

形狀

liquid

自燃溫度

752 °F

expl. lim.

6.4 %

折射率

n20/D 1.387 (lit.)

bp

57 °C (lit.)

mp

−40 °C (lit.)

密度

0.856 g/mL at 25 °C (lit.)

SMILES 字串

C[Si](C)(C)Cl

InChI

1S/C3H9ClSi/c1-5(2,3)4/h1-3H3

InChI 密鑰

IJOOHPMOJXWVHK-UHFFFAOYSA-N

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相关类别

一般說明

三甲基氯硅烷是一种氯-有机硅烷化合物,主要用于甲硅烷基化反应。

應用

三甲基氯硅烷已被用于使玻璃表面硅烷化,以增强其疏水性。它可以与六甲基二硅氮烷一起使用,通过甲硅烷基化反应形成三甲基甲硅烷基醚来保护醇。还用于Fisher糖基化

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

-18.4 °F - closed cup

閃點(°C)

-28 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles


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Use of organosilicon reagents as protective groups in organic synthesis.
Lalonde M & Chan TH.
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Magic-sized clusters (MSCs) can be isolated as intermediates in quantum dot (QD) synthesis, and they provide pivotal clues in understanding QD growth mechanisms. We report syntheses for two families of heterogeneous-atom-incorporated InP MSCs that have chlorine or zinc atoms. All
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Chemistry, an Asian journal, 11(22), 3225-3233 (2016-10-21)
Alkoxychlorosilanes are scientifically and industrially important toward preparing silicone and silica as well as preparation of siloxane-based nanomaterials by stepwise reactions of Si-OR (R=alkyl) and Si-Cl groups. Intermolecular exchange of alkoxy and chloro groups between alkoxysilanes and chlorosilanes (functional group

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