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Merck

P13800

Sigma-Aldrich

1-苯基乙醇

98%

别名:

(±)-1-苯乙醇, (±)-α-甲基苄醇, 甲基苯基甲醇, 苏合香醇, 苯乙烯醇

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$85.00
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$195.00
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$178.80

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25 G
$85.00
500 G
$195.00
1 KG
$178.80

About This Item

线性分子式:
C6H5CH(OH)CH3
CAS号:
分子量:
122.16
Beilstein:
1905149
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

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蒸汽密度

4.21 (vs air)

品質等級

蒸汽壓力

0.1 mmHg ( 20 °C)

化驗

98%

折射率

n20/D 1.527 (lit.)

bp

204 °C/745 mmHg (lit.)

mp

19-20 °C (lit.)

密度

1.012 g/mL at 25 °C (lit.)

SMILES 字串

CC(O)c1ccccc1

InChI

1S/C8H10O/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3

InChI 密鑰

WAPNOHKVXSQRPX-UHFFFAOYSA-N

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應用

  • 1-苯基乙醇可用于酸催化的 Ritter 反应,以合成各种 N-苄基乙酰胺。[1][2]
  • 它是通过钯催化的羟基取向环化合成 [60] 富勒烯稠合的异色满衍生物的关键前体之一。[3]
  • 它用于弗里德兰德喹啉合成反应,其中 1-苯基乙醇与 2-氨基苄醇衍生物反应生成相应的醌。[4]
  • 它也可用于区域选择性、铱催化的嘧啶多组分合成。[5]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

187.9 °F - Pensky-Martens closed cup

閃點(°C)

86.6 °C - Pensky-Martens closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Slide 1 of 1

1 of 1

Synthesis of [60] fullerene-fused tetrahydrobenzooxepine and isochroman derivatives via hydroxyl-directed C?H activation/C?O cyclization.
Zhai W Q, et al.
Organic Letters, 16(6), 1638-1641 (2014)
FeCl3-catalyzed Ritter reaction. Synthesis of amides.
Anxionnat B, et al.
Tetrahedron Letters, 50(26), 3470-3473 (2009)
Transition-metal-free indirect friedlander synthesis of quinolines from alcohols.
Martinez R, et al.
The Journal of Organic Chemistry, 73(24), 9778-9780 (2008)
The Ritter reaction under truly catalytic Br?nsted acid conditions.
Sanz R, et al.
European Journal of Organic Chemistry, 2007(28), 4642-4645 (2007)
A sustainable multicomponent pyrimidine synthesis.
Deibl N, et al.
Journal of the American Chemical Society, 137(40), 12804-12807 (2015)

Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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