694703

二(3,5-二叔丁基-4-甲氧基苯基)氯化膦

• 别名: Bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphinous chloride
• 经验公式（希尔记法）: C₃₀H₄₆ClO₂P
• CAS号: 212713-08-1
• 分子量: 505.11
• MDL编号: MFCD08458881
• UNSPSC代码: 12352112
• PubChem化学物质编号: 329761678
• NACRES: NA.22

属性

• 表单: solid
• 反应适用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 116-120 °C
• 官能团: phosphine
• SMILES字符串: COc1c(cc(cc1C(C)(C)C)P(Cl)c2cc(c(OC)c(c2)C(C)(C)C)C(C)(C)C)C(C)(C)C
• InChI: 1S/C30H46ClO2P/c1-27(2,3)21-15-19(16-22(25(21)32-13)28(4,5)6)34(31)20-17-23(29(7,8)9)26(33-14)24(18-20)30(10,11)12/h15-18H,1-14H3
• InChI key: VOGHMZHRQUWLRE-UHFFFAOYSA-N

说明

应用

Reactant for:

• Asymmetric hydrogenation with iridium catalysts
• Condensations with optically active diols
• Chemoselective reaction with deprotonated 2-hydoxy-3,3,N-trimethylbutanamide

Reactant for synthesis of:

• Phosphine-containing amino acids and peptide-based catalyst ligands
• Nonracemic phosphine-containing amino acids for palladium-catalyzed asymmetric allylic substitution reactions

法律信息

Kanata Chemical Technologies, Inc. 产品

安全信息

• 象形图: GHS02
• 警示用语：: Warning
• 危险声明: H228
• 预防措施声明: P210
• 危险分类: Flam. Sol. 2
• 储存分类代码: 4.1B - Flammable solid hazardous materials
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges