所有图片(1)

文件

912255

sBOX(tBu)

Name: sBOX(<I>t</I>Bu)
Brand: ALDRICH

≥95%

别名:

Di-tert-butyl 2,2′-(cyclopropane-1,1-diyl)(4S,4′S)-bis(4,5-dihydrooxazole-4-carboxylate)

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About This Item

经验公式（希尔记法）:

C₁₉H₂₈N₂O₆

CAS号:

2328084-27-9

分子量:

380.44

分類程式碼代碼:

12352005

NACRES:

NA.22

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406147

2,2′-异亚丙基双[(4S)-4-叔丁基-2-噁唑啉]

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Sigma-Aldrich

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sBOX(iPr)

Sigma-Aldrich

405000

(-)-2,2′-异亚丙基双[(4S)-4-苯基-2-噁唑啉]

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405973

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(S)-4-叔丁基-2-[2-(二苯基膦基)苯基]-2-噁唑啉

Sigma-Aldrich

464155

[3aR-[2(3′aR*,8′aS*),3′aβ,8′aβ]]-(+)-2,2′-亚甲基双[3a,8a-二氢-8H-茚并[1,2-]噁唑]

Sigma-Aldrich

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(R,R)-DACH-萘基 Trost 配体

Sigma-Aldrich

680192

2,2-双((4S)-(–)-4-异丙基噁唑啉)丙烷

Sigma-Aldrich

405965

2,2′-亚甲基双[(4S)-4-叔丁基-2-噁唑啉]

化驗

≥95%

形狀

powder or solid

mp

120.5 °C

儲存溫度

2-8°C

應用

sBOX(tBu) is a serine-derived chiral bisoxazoline ligand. The additional coordinating functionality provided by the esters enables new reactivity compared to traditional BOX ligands. sBOX(iPr) has been shown to be an optimal ligand for the electrocatalytic cyanophosphorylation as well as hydrocyanation of vinylarenes.

Product can be used with our Synlectro electrochemistry platform (ESYNTH001)

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes.

Niankai Fu et al.

Journal of the American Chemical Society, 141(37), 14480-14485 (2019-09-10)

In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new

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sBOX(tBu)