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Merck

283606

Sigma-Aldrich

氯化钯(II) 溶液

5 wt. % in 10 wt. % HCl

别名:

Dichloropalladium, Palladium dichloride, Palladous chloride

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50 ML
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About This Item

线性分子式:
PdCl2
CAS号:
分子量:
177.33
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

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表单

liquid

质量水平

反应适用性

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

浓度

5 wt. % in 10 wt. % HCl

密度

1.06 g/mL at 25 °C

SMILES字符串

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key

PIBWKRNGBLPSSY-UHFFFAOYSA-L

一般描述

氯化钯(II)是钯(II)的代表性盐,作为前体用于制备各种反应的钯催化剂,如 Heck 偶联、Suzuki 偶联、Sonagashira 偶联和 Buchwald-Hartwig 偶联。它也可用作氧化剂。

应用

用于合成含半导体金属的聚合物,其中聚吡咯骨架的构象能量最小并且几乎是平面结构。[1]

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Buyi Li et al.
Advanced materials (Deerfield Beach, Fla.), 24(25), 3390-3395 (2012-06-08)
Highly dispersed palladium chloride catalysts locked in triphenylphosphine-functionalized knitting aryl network polymers (KAPs) are developed and exhibit excellent activity under mild conditions in the Suzuki-Miyaura cross-coupling reactions of aryl chlorides in aqueous media. This work highlights that the microporous polymers
Ziwei Hu et al.
Chemical communications (Cambridge, England), 48(59), 7371-7373 (2012-06-21)
A base-controlled synthesis of 2-substituted secondary and tertiary 1H-indole-3-carboxamides through PdCl(2)-catalyzed cyclization of o-alkynyltrifluoroacetanilides followed by isocyanide insertion has been developed. The reaction proceeds smoothly at ambient temperature using O(2) in air as the sole oxidant of the palladium catalyst.
Juraj Velcicky et al.
Journal of the American Chemical Society, 133(18), 6948-6951 (2011-04-21)
A one-pot protocol for the cyanomethylation of aryl halides through a palladium-catalyzed reaction with isoxazole-4-boronic acid pinacol ester was developed. Mechanistically, the reaction proceeds through (1) Suzuki coupling, (2) base-induced fragmentation, and (3) deformylation as shown by characterization of all
Maozhong Miao et al.
Organic letters, 14(11), 2718-2721 (2012-05-16)
A novel PdCl(2)-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones, providing a facile synthesis of highly strained functionalized 2-alkylidenecyclobutanones via furan-fused cyclobutene intermediates, is reported. An interesting route to 2(3H)-furanones with a spiro-cyclopropane unit from the obtained 2-alkylidenecyclobutanones via a ring-contraction rearrangement reaction

Questions

  1. Does the 5 wt. % in 10 wt. % HCl mean PdCl2 weight percent or just the Pd weight percent? i.e if the solution weight is 100g, is the mass of Pd 5g or mass of PdCl2 5g?

    1 answer
    1. 5 wt% is the weight of PdCl2. If the solution weight is 100g, the mass of PdCl2 is 5g.

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