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Merck

192694

Sigma-Aldrich

异喹啉 N-氧化物

98%

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5 G
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5 G
$68.50

About This Item

经验公式(希尔记法):
C9H7NO
CAS号:
分子量:
145.16
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

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方案

98%

表单

solid

mp

103-105 °C (lit.)

SMILES字符串

[O-][n+]1ccc2ccccc2c1

InChI

1S/C9H7NO/c11-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H

InChI key

RZIAABRFQASVSW-UHFFFAOYSA-N

一般描述

已经通过稳定光照射和闪光光谱法研究了异喹啉N-氧化物在甲醇或水中的光化学异构化[1]。它是异喹啉衍生物的有用中间体[2]。在空气中的超声辐射下,它会导致富勒烯C60发生氧化[3]

应用

异喹啉N-氧化物被用于合成 N-烷氧基异喹啉鎓和N-烷氧基4-苯基吡啶鎓离子封端的聚苯乙烯[4]

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


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Iodine-mediated electrophilic cyclization of 2-alkynylbenzaldoximes leading to the formation of iodoisoquinoline N-oxides.
Huo Z, et al.
Tetrahedron Letters, 49(38), 5531-5533 (2008)
N-alkoxy pyridinium ion terminated polystyrenes: A facile route to photoinduced block copolymerization.
Durmaz YY, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 45(3), 423-428 (2007)
The primary photochemical process of isoquinoline N-oxide in hydroxylic solvents.
Ono I and Hata N.
Bulletin of the Chemical Society of Japan, 46, 3658-3662 (1973)
Weon-Bae Ko et al.
Ultrasonics, 42(1-9), 611-615 (2004-03-30)
The reaction of C60 with various amine N-oxides such as 3-picoline N-oxide (Aldrich 98.0%), pyridine N-oxide hydrate (Aldrich 95.0%), quinoline N-oxide (Aldrich 97.0%), isoquinoline N-oxide (Aldrich 98.0%) under ultrasonic irradiation in air at 25-43 degrees C causes the oxidation of
Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method

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