Przejdź do zawartości
Merck
Wszystkie zdjęcia(1)

Dokumenty

912409

Sigma-Aldrich

High-performance silicon anode

1 micron silicon particles in crosslinked conducting polyanaline matrix

Synonim(y):

Doped polyaniline, Si encapsulated in 3D crosslinked polyaniline, Si/PANi composite, Silicon micron particle

Zaloguj sięWyświetlanie cen organizacyjnych i kontraktowych
Wszystkie zdjęcia(1)

About This Item

Kod UNSPSC:
12352103
NACRES:
NA.23

Poziom jakości

100

Postać

solid

Szukasz podobnych produktów? Odwiedź Przewodnik dotyczący porównywania produktów

Zastosowanie

Silicon is a most promising next generation lithium ion battery electrode material, due to its ~10 times higher specific capacity (3600 mAh/g) than graphite (372 mAh/g). However, silicon experiences large volume change (~400%) during lithium insertion, causing it to fracture and detach from current collector, rendering prototypical lithium-silicon batteries to lose most of their capacity in less than 10 charge-discharge cycles. A solution to the capacity and stability issues posed by the significant volume expansion upon lithiation of silicon is critical to the success of high capacity lithium ion batteries.

This silicon/PANi composite utilizes a doped, intrinsically conductive, 3D cross-linked polyaniline as matrix, which could function as both the conductive binder and the polymer electrolyte for silicon-based electrodes. Previous study for a similar silicon-based three-dimensional conducting polymer composite demonstrated increased electrochemically performance due to short diffusion paths and good 3D connectivity, and resulted in a marked improvement in cyclability, with over 90% capacity retention after 5,000 cycles.

This composite is made by encapsulating silicon particles in an in-situ polymerized 3D-crosslinked conductive polyaniline framework. This Si/PANi composite not only allows fast electrical and ionic transport, but also provides free space to allow giant volume expansion. This Si/PANi composite provides a ready-to-use electrochemically active silicon composite that would increase the capacity of conventional lithium ion battery, and improve the cycle-life of Si-based anodes.
This page may contain text that has been machine translated.

Kod klasy składowania

11 - Combustible Solids

Klasa zagrożenia wodnego (WGK)

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

Certyfikaty analizy (CoA)

Poszukaj Certyfikaty analizy (CoA), wpisując numer partii/serii produktów. Numery serii i partii można znaleźć na etykiecie produktu po słowach „seria” lub „partia”.

Masz już ten produkt?

Dokumenty związane z niedawno zakupionymi produktami zostały zamieszczone w Bibliotece dokumentów.

Odwiedź Bibliotekę dokumentów

Deformation and stress in electrode materials for Li-ion batteries.
Mukhopadhyay A, et al.
Progress in Materials Science, 63, 58-116 (2014)
Borui Liu et al.
Nano letters, 13(7), 3414-3419 (2013-06-22)
Silicon is considered one of the most promising anode materials for high-performance Li-ion batteries due to its 4200 mAh/g theoretical specific capacity, relative abundance, low cost, and environmental benignity. However, silicon experiences a dramatic volume change (∼300%) during full charge/discharge
Fei Zhao et al.
Advanced materials (Deerfield Beach, Fla.), 30(48), e1801796-e1801796 (2018-08-21)
Nanostructured materials are critically important in many areas of technology because of their unusual physical/chemical properties due to confined dimensions. Owing to their intrinsic hierarchical micro-/nanostructures, unique chemical/physical properties, and tailorable functionalities, hydrogels and their derivatives have emerged as an
Ye Shi et al.
Nano letters, 17(3), 1906-1914 (2017-02-14)
Controlling architecture of electrode composites is of particular importance to optimize both electronic and ionic conduction within the entire electrode and improve the dispersion of active particles, thus achieving the best energy delivery from a battery. Electrodes based on conventional
Ye Shi et al.
Advanced materials (Deerfield Beach, Fla.), 29(22) (2017-03-23)
This study develops a tunable 3D nanostructured conductive gel framework as both binder and conductive framework for lithium ion batteries. A 3D nanostructured gel framework with continuous electron pathways can provide hierarchical pores for ion transport and form uniform coatings
Wyświetl wszystkie powiązane dokumenty

Produkty

Recent Developments in Silicon Anode Materials for High Performance Lithium-Ion Batteries

Recent demand for electric and hybrid vehicles, coupled with a reduction in prices, has caused lithium-ion batteries (LIBs) to become an increasingly popular form of rechargeable battery technology.

Najnowsze osiągnięcia w dziedzinie krzemowych materiałów anodowych dla wysokowydajnych akumulatorów litowo-jonowych

Niedawny popyt na pojazdy elektryczne i hybrydowe, w połączeniu z obniżką cen, spowodował, że akumulatory litowo-jonowe (LIB) stały się coraz bardziej popularną formą technologii akumulatorów.

Nasz zespół naukowców ma doświadczenie we wszystkich obszarach badań, w tym w naukach przyrodniczych, materiałoznawstwie, syntezie chemicznej, chromatografii, analityce i wielu innych dziedzinach.

Skontaktuj się z zespołem ds. pomocy technicznej