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Merck

243973

Sigma-Aldrich

亚硫酸氢钠

ACS reagent

别名:

酸式亚硫酸钠

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About This Item

经验公式(希尔记法):
NaHSO3
CAS号:
分子量:
104.06
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.21
等級:
ACS reagent
形狀:
powder or crystals
价格与库存信息目前不能提供

等級

ACS reagent

品質等級

形狀

powder or crystals

濃度

≥58.5% SO2

雜質

≤0.005% insolubles

pH值

4.3 (10 g/L)

負離子痕跡

chloride (Cl-): ≤0.02%

正離子痕跡

Fe: ≤0.002%
heavy metals (as Pb): ≤0.001%

SMILES 字串

[Na+].OS([O-])=O

InChI

1S/Na.H2O3S/c;1-4(2)3/h;(H2,1,2,3)/q+1;/p-2

InChI 密鑰

DWAQJAXMDSEUJJ-UHFFFAOYSA-L

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一般說明

亚硫酸氢钠的水溶液性质是酸性的。用酸降解亚硫酸氢钠形成二氧化硫气体。[1]
由于亚硫酸氢钠的抗氧化和抗菌作用,它是一种应用广泛的工业化学品,它可被用作还原剂、催化剂和防腐剂。

應用

亚硫酸氢钠可被用作:
  • 由芳香族和脂肪族醛合成醛-亚硫酸氢盐加合物的试剂。
  • 芳香族/脂肪醇无溶剂醚化通过分子间脱水合成对称和不对称醚的催化剂。
  • 铜催化酮肟羧酸盐自偶联合成对称吡咯的添加剂。
亚硫酸氢钠(NaHSO3)已用作组成免疫沉淀(IP)缓冲液的试剂,用于化学修饰 DNA[2] 和合成砷脂(AsL)。[3]
它还可用作合成 5,6-二氢尿嘧啶-6 的试剂磺酸盐。[4]

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Oral

安全危害

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Ledgard J.
The Preparatory Manual of Explosives., 87-87 (2007)
Hamid Mostafavi Abdolmaleky et al.
Methods in molecular biology (Clifton, N.J.), 448, 187-212 (2008-03-29)
Although there is evidence to link schizophrenia (SCZ) and bipolar disorder (BD) to genetic and environmental factors, specific individual or groups of genes/factors causative of the disease have been elusive to the research community. An understanding of the molecular aberrations
Wei Zhou et al.
Journal of Korean medical science, 24(1), 97-103 (2009-03-10)
Epithelial membrane protein 3 (EMP3) is a trans-membrane signaling molecule with important roles in the regulation of apoptosis, differentiation and invasion of cancer cells, but the detailed is largely still unknown. We analyzed the mRNA levels and methylation statuses of
Synthesis of two new arsenolipids and their identification in fish.
Arroyo-Abad U, et al.
European Journal of Lipid Science and Technology, 118(3), 445-452 (2015)
Miyako Yoshida et al.
Chemical & pharmaceutical bulletin, 61(1), 1-7 (2012-11-06)
The purpose of this study was to predict the stability of imipenem in a mixed infusion. The hydrolysis of imipenem in aqueous solution was found to be accelerated by pH, and by increasing concentrations of sodium bisulfite (SBS) and L-cysteine.

Questions

1–4 of 4 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. Dear Sir / Madame, I would kindly ask you to tell me what is the shelf life of the Sodium Bisulfite, no. 243973, batch no. MKCN9017. In the Certificate of Analysis is not specified the date the product expires. Thank you.

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

      Helpful?

  3. i just want to know that nahso3 assay is 58.5% SO2 in figure but, in msds it was marked assay 95~100%. i don't know reason why. please, explain it to me. assay값의 표기가 58.5% So2로 되어있는데, 실제 MSDS를 보면 95~100%라고 되어있어서 혼동되어 질문드립니다. 혹시 나머지 41.5%는 다른 물질인가요?

    1 answer
    1. The concentration on the Material Safety Data Sheet is in reference to what is in the bottle. There is no preservative or solvent added or included. This is essentially a pure preparation of NaHSO3. This is not a specification. The purity of the product is measured by titration as % SO2. The concentration on the webpage is the purity specification and refers to the % SO2 which is greater than or equal to 58.5%.

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  4. How can I determine the shelf life / expiration / retest date of this product?

    0 answers

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